protective equipment compartments.

专利摘要:
protective compartments for biomass equipment (eg plant biomass, animal biomass and municipal waste biomass) are processed to produce intermediates and useful products, such as energy, fuels, food or materials. for example, systems and methods are described, which can be used to treat raw material materials, such as cellulosic and / or lignocellulosic materials, in a safe, where the equipment is protected against radiation and dangerous gases by equipment compartments. equipment compartments can be purged with gas
公开号:BR112015006978A2
申请号:R112015006978
申请日:2013-10-10
公开日:2020-03-10
发明作者:Medoff Marshall；Paradis Robert；Craig Masterman Thomas
申请人:Xyleco Inc；
IPC主号:

专利说明:

EQUIPMENT PROTECTIVE COMPARTMENTS [1] This order incorporates by reference the full release of the following provisional orders pending below: USSN 61 / 711,801 and USSN 61 / 711,807 both filed on October 10, 2012; co-pending provisional applications filed on March 8, 2013: USSN 61 / 774,684; USSN 61 / 774,773; USSN 61 / 774,731; USSN 61 / 774,735; USSN 61 / 774,740; USSN 61 / 774,744; USSN 61 / 774,746; USSN 61 / 774,750; USSN 61 / 774,752; USSN 61 / 774,754; USSN 61 / 774,775; USSN 61 / 774,780; USSN 61 / 774,761: USSN 61 / 774,723; and USSN 61 / 793,336, deposited on March 15, 2013.
BACKGROUND OF THE INVENTION [2] Many potential lignocellulosic raw materials are available today, including agricultural waste, woody biomass, municipal waste, seed oils or seed masses and macroalgae, to name a few. At the moment, such materials are often underutilized, being used, for example, as animal feed, organic composting materials, burned in cogeneration establishments or even landfilled.
[3] Crystalline lignocellulosic biomass includes crystalline cellulose fibrils embedded in a hemicellulose matrix, surrounded by lignin. This produces a compact matrix that is difficult to access by enzymes and other chemical, biochemical and / or biological processes. Cellulosic biomass materials (for example, biomass materials from which substantially all of the lignin has been removed) are more accessible to enzymes and other conversion processes, but even so, naturally occurring cellulosic materials often have low yields (with respect to theoretical yield) when in contact with hydrolysis enzymes. Lignocellulosic biomass is even more recalcltrant to the enzyme attack. In addition, each type of lignocellulosic biomass has its own specific composition of cellulose, hemicellulose and lignin.
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SUMMARY [4] This invention relates to the systems, methods and processing equipment used to produce products from a material, for example, a biomass material. Generally, methods include treating a recalcitrant © biomass with electron beams while transporting the material using one or more carriers in a safe and then biochemically and chemically processing the matter recalcitrant © reduced to, for example, ethanol, xylitol and other products. Radiation in the vault can cause damage to the processing equipment in the vault or the radiation can generate reactive gases, for example, ozone, which can also degrade processing equipment. This damage can present hazards due to equipment failure, as well as incurring costs due to reduced time and necessary repairs. Damage mitigation can be completed by compartmentalizing equipment and / or components of processing equipment in equipment compartments that are opaque to radiation and that can be removed with a gas that is inert to the components and / or equipment.
[5] In one aspect, the invention relates to a method of protecting processing equipment, for example, material (for example, biomass), biomass processing equipment and other auxiliary equipment that may be required for biomass irradiation. The processing equipment can include, for example, a vibrating conveyor for transporting a biomass material under an electron beam and the associated equipment necessary for the conveyor, especially which facilitates moving the biomass. This includes the equipment that provides vibration to the conveyor. Auxiliary conveyor parts include all the parts that are necessary to transport and, optionally, the vibrating part of the conveyor. The methods include compartmentalizing engine components of the vibrating conveyor in an equipment compartment substantially opaque to the
3/83 radiation (eg material including lead) while purging the equipment compartment with a gas. The method can reduce the engine's exposure to radiation compared to the radiation exposure that would occur without the equipment compartment. For example, radiation exposure to engines can be reduced by at least 10%, at least 20%, at least 30%, at least 50%, at least 70% or even more (for example, at least 90%).
[S] In some cases, the gas used in the methods may include, for example, air, oxygen reduced to air, inert gases, nitrogen, argon, helium, carbon dioxide and mixtures thereof. Optionally, the gas in the equipment compartment is changed at a time of change of at least 10 minutes (for example, once every 5 minutes, once every minute, every 30 seconds).
[7] In some cases, the method additionally includes moving the equipment compartment, for example, to access the engines, positioning the equipment compartments and / or adjusting the equipment compartment. The equipment compartment can be configured to be mobile (for example, mounted on wheels, rails, slides). Optionally, the method includes providing a gap between the equipment compartment and the vibrating conveyor to accommodate the vibration of the vibrating conveyor components during use and / or providing a path for airflow outside the equipment compartments.
[8] In some other cases, the method includes placing the equipment inside a biomass processing vault. For example, the method may include methods in which the vibrating conveyor is arranged inside a safe. In addition, and optionally, the method may include methods in which the safe contains irradiation equipment. Optionally, gas, for example, used to clean equipment compartments, is
4/83 provided from inside the safe. For example, gas supplied from inside the safe can be filtered or treated before purging equipment compartments (for example, to remove ozone and / or destroy ozone).
[9] In another aspect, the invention relates to a system protecting a motor, for example, a motor of a vibrating conveyor. The system includes a vibrating conveyor having motor components mounted on a planar structure and an equipment compartment substantially opaque to radiation configured to be positioned on the motor. The open end of the equipment compartment was dimensioned in order to provide a circumferential opening between the equipment compartment and the planar structure when the equipment compartment is in place. Optionally, the gap is maintained by the equipment compartment in relation to the conveyor using a limiter, a groove, a spacer and / or a fastener. the system may additionally include a conduit configured to flow a purge gas into the equipment compartment. Optionally, the system includes equipment for moving the equipment compartment in and out of position on the components, for example, including wheels attached to the equipment compartment, tracks for sliding the equipment compartment, wheels arranged below the equipment compartment ( for example, attached to the ground), slides (for example, slide rails), linear guides and their combinations. The engine components include the engine, support structures, conduits, piping and electrical components. This may include the equipment needed to move the compartments.
[10] In yet another aspect, the invention relates to a method for protecting biomass processing equipment. The method includes transporting a material, such as a biomass material, e.g. eg a lignocellulosic material, through a radiation field, such as under a beam
5/83 electrons in a vibrating conveyor. The method additionally includes compartmentalizing the motor components, for example, the motor components of the conveyor, such as a vibrating conveyor, in an equipment compartment substantially opaque to radiation. For additional protection, the equipment compartment can be purged with gas. such as air, nitrogen or combinations of these.
[11] The described equipment compartments are effective in protecting processing equipment / components used in the radiation processing of materials. The equipment compartments also provide a volume within which the atmosphere can be easily controlled, for example, exchanged or evacuated by ozone and / or other inert gases. The equipment compartments can be easy to build and durable, offering an economical solution for the incidental, accidental and or unintentional degradation of processing equipment due to radiation.
[12] Implementations of the invention may optionally include one or more of the characteristics summarized below. In some implementations, the selected features can be applied or used in any order, while in other implementations a specific selected sequence is applied or used. Individual characteristics can be applied or used more than once in any sequence. In addition, an entire sequence or part of a sequence, of resources used or applied, can be applied or used once or repeatedly in any order. In some optional implementations, these characteristics can be applied or used with different parameters, or, when applicable, with fixed or varied parameters, quantitative or qualitative, by a person skilled in the art. For example, parameters of characteristics such as size, individual dimensions (for example, length, width and height), location, degree (for example, to what extent, such as degree or
6/83 recalcitrance), duration, frequency of use, density, concentration, intensity or speed can be varied or fixed, when applicable, as determined by a person skilled in the art.
[13] Features include, for example, a method for protecting material processing equipment, transporting a biomass material under an electron beam on a conveyor, and compartmenting the conveyor's engine components in a radiation-opaque equipment compartment, for example , while purging the compartment with a gas and where the gas can be air. The gas in the equipment compartment is changed at a rate of less than once every 10 minutes. The gas used to purge the equipment compartment can be air, oxygen reduced to air, nitrogen, argon, helium, carbon dioxide and mixtures, [14] The conveyor for transporting biomass is typically inside a safe. The irradiation equipment may also be in the safe. The gas that is used to purge the equipment compartment can come from inside the safe and can be filtered before using it in the equipment compartment. Gas filtration can include ozone removal. There is also a conduit configured to flow the purge gas into the equipment compartment. The conveyor can be a vibrating conveyor.
[15] The equipment compartment is movable so that there can be access to motors such as vibrating motors. The equipment compartment and the conveyor are configured to accommodate the movement of the components when the conveyor is a vibrating conveyor and there may be a gap between the equipment compartment and the vibrating conveyor equipment, especially the motor. The vibrating conveyor having motor components is mounted on a frame; such that when the equipment compartment is
7/83 in position to protect the engine equipment there is a gap provided between the structure and the equipment compartment. This gap is maintained by the equipment compartment in relation to the conveyor using a limiter, a groove, a spacer and / or a fastener. In addition, equipment is provided to move the equipment compartment in and out of positions on the conveyor components. The equipment for moving the equipment compartment can be wheels, tracks, slide rails, linear guides and their combinations.
[16] The equipment compartment can reduce the amount of radiation exposure that transport equipment receives by at least 10% when compared to no equipment compartment. Alternatively, the reduction in radiation exposure maybe at least 20%, optionally, at least 30%, or more, optionally, at least 50% and more at least 70% and, alternatively, at least 90% reduction in radiation exposure .
[17] Other features and advantages of the invention will be evident from the following detailed description and claims.
DESCRIPTION OF THE FIGURE [18] The foregoing will become apparent from the more detailed description below and exemplary modalities of the invention, as illustrated in the accompanying one. The figures are not necessarily in adequate proportion, with the emphasis being placed instead on illustrating modalities of the present invention.
[19] FIG. 1 is a sectional perspective view of a safe with compartments to protect components from biomass conveyors.
[20] FIG. 2A is a perspective view of a vibrating conveyor including equipment compartments to protect the engine.
8/83 conveyor components. Figures 28 and 2C are detailed perspective views of an equipment compartment.
[21] FIG. 3A is a perspective view of a conduit. FIG. 3B is an axial cross-sectional view of the conduit. FIG. 3C is a radial cross-sectional view of conduit taken along line 3C-3C in FIG. 3A.
DETAILED DESCRIPTION [22] Use the methods and systems described in this document, materials from oelulosic or lignocellulosic raw materials, for example, which can be extracted from biomass (eg plant biomass, animal biomass, paper and municipal waste biomass) and which are often readily available but difficult to process, can be turned into useful products (for example, sugars such as xylose and glucose, alcohols such as ethanol and butanol). Included are methods and systems for treating biomass with radiation in which the processing equipment and / or components of the processing equipment are combined in radiation-opaque equipment compartments. In preferred implementations the equipment compartments are purged with a gas that is inert to the components and / or equipment.
[23] Many processes for the manufacture of sugar solutions and products derived therefrom are described in this document. Such processes may include, for example, optionally mechanically treating a cellulosic and / or lignocellulosic raw material. Before and / or after this treatment, the raw material can be treated with another physical treatment, for example, irradiation, steam explosion, pyrolysis, sonication and / or oxidation to reduce or further reduce its recalcitrance. A sugar solution is formed by saccharifying the raw material through, for example, the addition of one or more enzymes. A product can be
9/83 derived from the sugar solution, for example, by fermentation of an alcohol · Further processing may include purifying the solution, for example, by distillation. If desired, steps for measuring lignin content and configuring or adjusting process parameters (eg irradiation dosage) based on this measurement can be performed at various stages of the process, for example, as described in the Serial Order Number US 12 / 704,519, filed on February 11, 2011, the full disclosure of which is incorporated herein by reference.
[24] Since the processing step of the recalcitrants can be a high energy process, the treatment can be carried out in a safe and / or shelter to contain the energy and / or some of the products derived from the energy process, which can be dangerous. For example, the safe can be configured to contain thermal energy, electrical energy (for example, high voltages, electrical discharges), radiation energy (for example, x-rays, particle acceleration, gamma rays, ultraviolet radiation), energy explosion (eg a shock wave, projectiles, blowing the wind), gases (eg, ozone, steam, nitrogen oxides and / or volatile organic compounds) and combinations of these. Although this containment in a safe protects people and equipment outside the safe, the equipment inside the safe is subjected to energy and / or products derived from the energy process. In some cases, this safe containment may exacerbate the effects, for example, by not allowing the dissipation of gases (for example, ozone, steam, nitrogen oxides and / or volatile organic compounds), or by providing reflective surfaces for radiation, or the safe can provide reflective surfaces for shock waves due to an explosion, or the compartment can provide insulation causing the temperature in the safe to be high. The interior of the safe during operation, therefore, can be a harmful environment. The risks to humans are mitigated, ensuring that no one is in the safe during the operation. Risks to the equipment can be
10/83 attenuated, compartmentalizing the equipment or equipment components in protection compartments inside the safe and / or shelter.
[25] If treatment methods to reduce recalcitrance include irradiation of the raw material, for example, with ionizing radiation, intentional irradiation of the equipment inside the safe may occur. For example, an electron beam hitting a material can create x-rays through the breakdown of radiation (Bremsstrahlung) which can also be ionizing depending on its energy. For example, irradiation of a biomass feedstock onto a conveyor surface made of a metal (for example, stainless steel) would create x-rays, especially when electrons reach the metal surface. The production of x-rays when there is no biomass, or less than enough biomass to cover the surface of the conveyor, would be particularly strong, for example during startup, shutdown or when the process is operating outside its normal parameters .
[26] In addition, electron beams can produce ozone by irradiating oxygen (for example, oxygen in the air). Ozone is a strong oxidizer, with a 2.07 V redox potential (vs the standard hydrogen electrode), superior to other strong oxidizers known as hydrogen peroxide, permanganate, chlorine gas and hypochlorite with 1.77V redox potentials , 1.67V, 1.36v and 0.94V, respectively. Therefore, materials, for example, organic materials, are susceptible to degradation by ionizing radiation and oxidation by ozone. For example, materials can degrade through chain splitting, crosslinking, oxidation and heating. In addition, metal components are susceptible to oxidation and degradation by ozone, causing them, for example, to corrode / perforate and / or rust.
[27] Therefore, equipment that includes polymers and some metals (for example, excluding perhaps corrosion-resistant or noble metals) can
11/83 be damaged. For example, damage can occur to belts that include organic material, for example those used in equipment, for example, such as the coupling between a drive motor and an eccentric flying wheel of a vibrating conveyor. (Vibrating conveyors are described in Provisional U.S. Serial Number 61 / 711,807 filed on October 10, 2012, the full disclosure of which is incorporated by reference in this document). Engine systems and / or components that may be susceptible to damage by ozone and radiation include, for example, wheels, bearings, springs, shock absorbers, solenoids, actuators, switches, gears, shafts, washers, adhesives, fasteners, screws, nuts, screws, brackets, frames, pulleys, covers, vibration dampers, slides, filters, openings, pistons, fans, fan blades, wires, wire coatings, valves, transmission shafts, computer chips, microprocessors, circuit boards and cables. Some organic materials can be degraded by ionizing radiation and ozone includes thermoplastics and thermosets. For example, organic materials that may be susceptible to damage include phenolic compounds (eg, bakelite) fluorinated hydrocarbons (eg, Teflon), thermoplastics. polyamides, polyesters, polyurethanes, rubbers (for example, butyl rubber, dorado polyethylene, polynorbornene), polyethers, polyethylene (Linear low density polyethylene, high density polyethylene), polyesters, polyvinyls (for example, polyvinyl chloride), cellulosic, amino resins (eg urea-formaldehyde), polyamines, polyurethanes, polyamides, acrylics (eg methyl methacrylate), acetal lubricants (eg polyoxymethylene) (eg oils and gels), destructive polysiloxanes and combinations thereof .
[28] Protecting the equipment may include the materials discussed above or other materials or equipment described in this document, the invention includes compartmentalizing and / or protecting the materials from radiation
12/83 using radiation-opaque materials. In some implementations, radiation-opaque materials are selected to be able to protect x-ray components with high energy (short wavelength), which can penetrate many materials. An important fact in the design of a radiation insulation compartment is the attenuation length of the materials used, which will determine the thickness required for a particular material, mix of materials, or layered structures. The attenuation length is the penetration distance over which the radiation is reduced by approximately 1 / e (e ~ Euler number) times that of the incident radiation. Although virtually all materials are radiation-opaque if thick enough, materials containing a high compositional percentage (eg density) of elements that have a high Z value (atomic number) have a shorter radiation attenuation length, and thus , if such materials are used, a thinner and lighter compartment can be provided. Examples of materials with a high Z value that are used in radiation insulation are tantalum and lead. Another important parameter in radiation isolation is the semi-reducing distance, which is the thickness required for a particular material to reduce the intensity of gamma rays by 50%. As an example of X-ray radiation with an energy of 0.1 MeV, the semi-reducing distance is about 15.1 mm for concrete, and about 0.27 mm for lead, while with X-ray energy. x, of 1 MeV, the semi-reducing distance of concrete is about 44.45 mm and for lead it is about 7.9 mm. Radiation-opaque materials can be materials that are thick or thin, as long as they can reduce the radiation that passes through the other side. Thus, if desired, a particular compartment may have a low wall thickness, for example, for light weight or due to size restrictions, the chosen material must have a sufficient Z value and / or attenuation distance so that its semi layer -reducer is less than or equal to the wall thickness of the
13/83 desired compartment.
[29] In some cases, radiation-opaque material can be a material! layered, for example, having a layer of a material with a higher Z value, to provide good shielding, and a layer of a material with a lower Z value to provide other properties (e.g., structural integrity, impact resistance, etc,). In some cases, the layered material may be a “grade” Z laminate, for example, including a laminate in which the layers provide a high Z gradation for successive low Z elements.
[30] Radiation-opaque material can reduce radiation by passing through the structure (for example, a wall, door, ceiling, compartment, a series or combination of these) formed by a material of at least about 10%, (for example example, at least about 20%, at least about 30%, at least about 40%, at least about 50%, at least about 60%, at least about 70%, at least about at least at least about 80%, at least about 90%, at least about 95%, at least about 96%, at least about 97%, at least about 98%, at least about 99%, at least about 99.9%, at least about 99.99%, at least about 99.999%), compared to incident radiation. Therefore, an equipment compartment made of a material opaque to radiation can reduce the exposure of the equipment / system / components by the same amount. Materials opaque to radiation may include stainless steel, metals with Z values above 25 (for example, lead, iron), concrete, earth, sand and combinations thereof. Materials opaque to radiation may include a barrier in the direction of incident radiation of at least about 1 mm (for example, 5 mm, 10 mm, 5 cm, 10 cm, 100 cm, 1 m, 10 m).
[31] The materials chosen for being opaque to radiation can be chosen, along with their radiation attenuation properties,
14/83 based on your other duties. For example, the walls of a safe that can support a heavy ceiling and / or equipment and can rarely, if necessary, be moved can be constructed of concrete. A safe door would preferably be made relatively thin and light and easy to open and close (for example, hinged or in a strip) and can be made of layers, including iron and lead. Preferably, the compartments for systems / equipment / components described in this document would need to be relatively small and mobile. For example, they must be moved by light equipment, such as small fork lifts, motorized pulleys, or manually by one person. The weight, therefore, should be less than about 2000 kg (for example, less than about 1000 kg, less than about 900 kg, less than about 800 kg, less than about 700 kg, less than about 600 kg kg, less than about 500 kg, less than about 400 kg, less than about 300 kg, less than about 200 kg, less than 100 kg, less than about 50 kg, less than about 25 kg). The construction can include lead, stainless steel and other metals with Z numbers over 25. The compartments can include layers of materials, for example, lead and stainless steel, where lead can provide radiation protection while stainless steel! can provide better structural properties.
[32] In some cases the compartments are mounted to be easily moved and / or removed. For example, compartments can be mounted and / or suspended on wheels (for example, casters), rails, pulleys and hinges. The compartments can also be partitioned in the quasas and the partitions can be mounted or disassembled around equipment / system / component to be compartmentalized. Part of the compartment can be integrated with the system / equipment / component to be included. For example, the equipment can be mounted on a plate that is protective and configured to couple with the compartment. Compartments can
1S / 83 to be attached to the equipment, for example, by hooks, screws, screws, straps, snap type fitting, or other fastening elements.
[33] One or more compartments can be used in a component, for example, an inner compartment surrounded by an outer compartment (or several outer ones). The compartments can be of any shape and can include walls that are curved, flat, rough, smooth, spherical or angled. The compartment includes tubes and ducts. The compartments can be configured to be combined., For example, to make a larger compartment or to form different parts of a compartment (for example, a tube can compartmentalize part of the equipment, a box compartmentalizing a second equipment).
[34] To protect the equipment, including metals and organics, as discussed above from ozone, the compartments for the equipment are configured to be purged by a gas flow that is ozone-free, or with less ozone than would be present during an irradiation process. This purge is particularly useful in cases where the compartment cannot be readily sealed around the item to be protected, for example, in the case of equipment that is moving and / or vibrating, such as the motor of a vibrating conveyor. In this case, the presence of the purge gas in the equipment compartment excludes the entry of particles or other gases (for example, ozone), which otherwise could enter the unsealed equipment compartment. In some implementations, each compartment has one or more inlets to allow a purge gas to enter and one or more outlets for the purge gas to escape. The purge gas can come from outside a safe that contains the irradiation equipment and can be, for example, atmospheric air, tank air, nitrogen, argon, helium or combinations of these. The purge gas can optionally come from inside the safe, although preferably if air from the safe is
16/83 used, the air must be treated, for example, filtered through an ozone reduction filter (for example, including a carbon filter). The air flow must be sufficient to keep any ozone that is present outside the compartment from entering the compartment. For example, the exchange rate in the compartment (the time it takes for the volume of air to enter and exit the compartment to equal the total volume of the compartment) is, for example, less than approximately 10 min (for example, less than than 9 min, less than 8 min, less than about 7 min, less than about 6 min, less than about 5 min, less than about 4 min, less than about 3 min, less than about 2 min, less than about 1 min, less than 30 seconds, less than 10 seconds, less than about 1 second). Alternatively or additionally, the pressure inside the compartment can be slightly higher than the outside, for example, at least about 0.0001% (for example, at least about 0.001%, at least about 0.01%, at least about 0.1%, at least about 1%, at least about 10%, at least about 50%, at least about 100%). Alternatively or additionally the average flow of the purge gas to the outlet of the compartment is at least 0.1 mlcm-2 s-1 (for example, at least approximately 0.5 mlcm-2 s-1, at least approximately 1, 0 mLcm-2 s-1, at least about 2.0 mLcm-2 s-1, at least about 5.0 mLcm-2 s-1, at least about 10 mLcm-2 s-1, at least about 20 mLcm-2 s-1, at least about 30 mLcm-2 s-1 at least about 40 mLcm-2 s-1, at least about 50 mLcm-2 s-1, at least 60 mLcm-2 s- 1, at least about 70 mLcm-2 s-1, at least about 80 mLcm-2 s-1, at least about 90 mLcm-2 s-1, at least about 100 mLcm-2 s-1) .
[35] In some embodiments, the purge gas can be a refrigerant gas, for example, the flow providing cooling to the engine components. For example, the gas can be cooled before being sent into the compartment or it can be from a
17/83 cooled source (for example, blowing liquid nitrogen).
[36] An embodiment of the invention is shown with reference to Fig. 1, which is a perspective view of a safe with protective mechanical components for carrier compartments. The ceiling / roof is not shown in this view so that the interior of the safe can be seen more clearly. Boxes 112 and 114 are positioned next to a first conveyor 116. Boxes 122 and 124 are positioned next to a second transmitter 126. Conduits for electrical cables and / or gas (eg, air, nitrogen) for the boxes as well are shown as tubes, 118, 120, 128 and 130, extending below the ceiling. The tubes, 118, 120, 128 and 130 go through the roof. The boxes and conduits are made from materials opaque to radiation, protecting the components inside the box (for example, motors and associated belts that drive the conveyors) from radiation and are examples of a compartment to protect equipment / systems and / or components.
[37] In use, biomass is transported into the safe and on the first conveyor through a drip opening 140 connected to the outside of the safe by a tube (not shown), passing through the ceiling. The biomass travels in the direction shown by the arrow and is dripped onto the second conveyor. The second conveyor carries the biomass under the verification rod 142. The verification rod is connected to a high vacuum electron conduit 144, through the roof and a electron accelerator 146. The electron accelerator and power source 148 are supported by the roof of the safe. The atmosphere inside the vault contains high levels of ozone due to electron radiation from atmospheric oxygen during the process. When purging the boxes through their respective conduits with a fluid that contains less ozone than that in the safe atmosphere, the ozone in the vicinity of the mechanical components for the conveyors is reduced. The liquid can be, for example, atmospheric air, nitrogen,
18/83 hydrogen, helium, safe air that has been treated to reduce the level of ozone and mixtures of these. When the air that is used to purge the compartments is safe air that has been treated to reduce the ozone layer, the conduit for the purge gas does not need to be passed through the roof and can be part of a system, including a pump and a filter (for example, an ozone filter) to remove ozone-laden air and pump ozone-free air out (into the compartment).
[38] FIG. 2A is a figure of a vibrating conveyor 116 with boxes 114 and 112 for covering mechanical components. The boxes are shown mounted on tracks 212 and 214 using wheels, for example, 222 and 224. The boxes can be moved on tracks in the directions indicated by the double head arrow. In this view, the boxes are away from the conveyor, showing engine component 232. Conduit for electrical and / or purge gas are shown as 118 and 120 attached to the conveyor. When the conveyor is in operation, the boxes are pushed close to plates 250 and 251, compartmentalizing the engine component. Preferably the edge 258 of the box is not in contact with the plate since the friction caused by the oscillation of the conveyor (and attached plate) against the edge of the box when the conveyor is in operation, would cause wear and heating. X-rays are shown in an arbitrary location to the x-rays that are formed when the electron beam hits the material, especially the surface of a metal as a carrier that has no biomass in it. In addition, the gap between the edge of the box and the plate provides a flow path out of the equipment compartment so that the equipment compartment can be purged. For example, an average gap between the edge and the plate is preferably between Imm and 60 mm (for example, between about 1-5mm, 1-1 Omm, 1-20mm, 1-30mm, 140mm, 2-1 Omm, 2-20mm, 2-30mm, 2-40mm, 2-50mm, 3-1mm, 3-20mm, 330mm, 3-40mm, 3 ~ 50mm, 4-1mm, 4 ~ 20mm, 4-30mm, 4 ~ 40mm, 4-50mm,
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5 ~ 10mm, 5-20mm, 5-30mm, 5-40mm, 5 '50mm, 10-20mm ₍ 10-30mm, 10 ~ 40mm). Slots 252 and 254 accommodate conduits 118 and 120 respectively so that the box and plate can form an equipment compartment with only a minimum gap (for example, similar to the gap between the plate and the edge of the box) between the plates / conduits and boxes.
[39] FIG. 2B is a close-up view of box 114 in perspective showing the edge of opening 258 for accepting vibrating conveyor components, for example, a motor component. Rail 212 has stoppers 242 and 244 that can secure the box in the desired position on the rails.
[40] FIG. 20 is another perspective view of the boxes. The box includes handles 262 and 264 which can be useful for securing boxes when they need to be moved.
[41] In other embodiments, the gap between the equipment compartment and the vibrating conveyor can be maintained by methods other than the one disclosed above. For example, the equipment compartment can be defined in a depression that is configured to accept the presence of the equipment compartment, mobile limiters could be fixed by, for example, friction or fasteners (for example, pins, screws), to the floor and keep the equipment compartments in place. The equipment compartment could have casters that fit into a depression or against limiters. Magnetic limiters can also be used. In some embodiments, the boxes could be suspended from the ceiling or a wall by structures (for example, cooled structures, steel frames, beams, depressions in the wall, cables and combinations thereof) in the desired position. The equipment compartments could also be mounted on the vibrator while leaving the gap when using spacers,
20/83 as well as fasteners. In some oases, the equipment compartments can be included as part of the conveyors, for example, they could be covers for engines that are made of materials opaque to radiation and have an inlet and outlet for purging with a gas.
[42] FIG, 3A is a perspective view of conduit 118 showing a cable 312 disposed thereon. The can be an insulated electrical cable for supplying electrical power and signals to an engine. The cable could also include a mechanical cable, for example, to mechanically operate a switch (for example, emergency shutdown). Although FIG. 3A showing only one cable, multiple cables and / or wires can be arranged in the conduit. FIGs. 38 and 3C are axial and radial transversal views, respectively. of the conduit, showing the cable 312 in place inside the internal cavity 314, the cable 312 passes through the conduit, but does not fill the conduit so that a flow of gas through the conduit can be accommodated, as indicated by the arrows in FIG. 3B.
RADIATION TREATMENT [43] The raw material can be treated with electron bombardment to modify its structure to reduce its recalcitrance. Such treatment can, for example, reduce the average molecular weight of the raw material, alter the crystalline structure of the raw material and / or increase the surface area and / or porosity of the raw material.
[44] Electron bombardment through an electron beam is generally preferred, as it provides very high throughput. Electron beam accelerators are available, for example, from IBA, Belgium and NHV Corporation, Japan.
[45] Electron bombardment can be accomplished using an electron beam device that has a nominal energy of less than
21/83
MeV, for example, less than 7 MeV, less than 5 MeV and less than 2 MeV, for example, approximately 0.5 to 1.5 MeV, approximately 0.8 to 1.8 MeV, approximately 0.7 to 1 MeV. In some implementations the nominal energy is around 500 to 800 keV.
[46] The electron beam can have a relatively high total beam power (the combined beam power of all accelerator heads, or, if multiple accelerators are used, from all accelerators and all heads), for example example, at least 25 kW _; for example, at least 30, 40, 50, 60, 65, 70, 80, 100, 125 or 150 kW. In some cases, the power is as high as 500 kW, 750 kW, or even 1000 kW or more. In some cases, the electron beam has a beam power of 1200 kW or more, for example, 1400, 1600, 1800, or up to 300 kW.
[47] This high total beam power is usually achieved using multiple acceleration heads. For example, the electron beam device can include two, four, or more acceleration heads. The use of multiple heads, each of which has a relatively low beam power, prevents excessive temperature rise of the material, thus preventing burning of the material and also increasing the uniformity of the dose through the thickness of the material layer.
[48] It is generally preferred that the bed of biomass material has a relatively uniform thickness. In some embodiments, the thickness is less than about 1 inch (for example, less than about 0.75 inches, less than about 0.5 inches, less than about 0.25 inches, less than about 0, 1 inches, between about 0.1 and 1 inch, between about 0.2 and 0.3 inches).
[49] In some implementations, it is desirable to cool the material during and between material dosing with electron bombardment.
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For example, the material can be cooled while it is being transported, for example by a screw extruder, vibrating conveyor or other transport equipment. For example, refrigeration while in transit is described in US Provisional Order No. 61/774735 and US Provisional Order No.® 61 / 774.752, the entire description of which is incorporated herein by reference.
[50] To reduce the energy required by the recalcitrance reduction process, it is desirable to treat the material as quickly as possible. In general, it is preferable that the treatment be carried out at a dose rate greater than approximately 0.25 Mrad per second, for example, greater than approximately 0.5, 0.75, 1, 1.5, 2, 5, 7, 10, 12, 15 , or even greater than approximately 20 Mrad per second, for example, approximately 0.25 to 2 Mrad per second. Higher dose rates allow for a higher flow rate to the target dose (for example, desired). Higher dose rates generally require higher line speed to avoid thermal decomposition of the material. In one implementation, the throttle is set to a beam current of 3 MeV, 50mA, and the line speed is 24 feet / minute, for a sample thickness of about 20 mm (for example, spike material). crushed corn with a density of 0.5 g / cm ³ ).
[51] In some embodiments, electron bombardment is performed until the material receives a total dose of at least 0.1 Mrad, 0.25 Mrad, 1 Mrad, 5 Mrad, for example, at least 10, 20, 30 or at least 40 Mrad. In some embodiments, treatment is carried out until the material receives a dose of about 10 Mrad to about 50 Mrad, for example, from about 20Mrad to about 40 Mrad, or about 25 Mrad to about 30 Mrad . In some implementations, a total dose of 25 to 35 Mrad is preferred, ideally applied for a few seconds, for example, at 5 Mrad / pass with each pass being applied for approximately one second. Apply a dose of more than 7
23/83 to 8 Mrad / passage can in some cases cause thermal degradation of the raw material material. Cooling can be applied before, during or after irradiation. For example, refrigeration methods, systems and equipment may be used as described in the following orders: U.S. Provisional Order No. 61 / 774,735 and U.S. Provisional Order No. 61 / 774,754 disclosures are incorporated by reference in this document in their entirety.
[52] Using multiple heads, as discussed above, the material can be treated in several passes, for example, two passes of 10 to 20 Mrad / pass, for example, 12 to 18 Mrad / pass, separated by a few seconds of cooling, or three passes from 7 to 12 Mrad / ticket, for example, 5 to 20 Mrad / ticket, 10 to 40 Mrad / ticket, 9 to 11 Mrad / ticket. As discussed in this document, treating the material with several relatively low doses, instead of a high dose, tends to prevent the material from overheating and also increases dose uniformity across the thickness of the material. In some implementations, the material is agitated or otherwise mixed during or after each pass and then spread on an even layer before the next pass, to further increase the uniformity of treatment.
[53] In some embodiments, electrons are accelerated to, for example, a speed of more than 75 percent of the speed of light, for example, greater than 85, 90, 95, or 99 percent of the speed of light.
[54] In some embodiments, any processing described in this document takes place on lignocellulosic material that remains dry as purchased or that has been dried, for example, using heat and / or reduced pressure. For example, in some embodiments, cellulosic and / or lignocellulosic material has less than 25% by weight of water retained, measured at 25 ° C and a relative humidity of fifty percent (for example, less than
24/83 about 20% by weight, less than about 15% by weight, less than about 14% by weight, less than about 13% by weight, less than about 12% by weight, less than about 10% by weight, less than about 9% by weight, less than about 8% by weight, less than about 7% by weight, less than about 6% by weight, % by weight less than about 5% by weight, less than about 4% by weight, less than about 3% by weight, less than about 2% by weight, less than about 1% by weight , less than about 0.5% by weight, less than about 15% by weight.
[55] In some embodiments, two or more electron sources are used, such as two or more ionizing sources. For example, samples can be treated, in any order, with an electron beam, followed by gamma radiation and UV light with wavelengths from about 100 nm to about 280 nm. In some embodiments, the samples are treated with three sources of ionizing radiation, such as an electron beam, gamma radiation, and energetic UV light. The biomass is transmitted through the treatment zone, where it can be bombarded with electrons.
[56] It may be advantageous to repeat the treatment to totally reduce the recalcitrance of the biomass and / or modify the biomass. In particular, the process parameters can be adjusted after a first pass (for example, second, third, fourth or more) depending on the recalcitrance of the material. In some embodiments, a conveyor can be used which includes a recirculating system in which the biomass is transmitted several times through the various processes described above. In some other embodiments, various treatment devices (for example, electron beam generators) are used to treat biomass several times (for example, 2, 3, 4 or more). In still other embodiments, a single electron beam generator can be the source of multiple beams (for example, 2, 3, 4 or more beams) that can be used
25/83 for the treatment of biomass.
[57] The effectiveness to alter the molecular / supermolecular structure and / or to reduce the recalcitrance of the biomass containing carbohydrate depends on the electron energy used and the applied dose, while the exposure time depends on the power and the dose. In some embodiments, the dose rate and total dose are adjusted so as not to destroy (for example, carbonize or burn) the biomass material. For example, carbohydrates must not be damaged in processing, so that they can be released from biomass intact, e.g., as monomeric sugars.
[58] In some embodiments, treatment (with any electron source or a combination of sources) is carried out until the material receives a dose of at least approximately 0.05 Mrad, for example, at least approximately 0.1, 0 , 25, 0.5, 0.75, 1.0, 2.5, 5.0, 7.5, 10.0, 15, 20, 25, 30, 40, 50, 60, 70, 80, 90 100, 125, 150, 175 or 200 Mrad. In some embodiments, treatment is carried out until the material receives a dose of between 0.1-100 Mrad, 1-200, 5-200, 10-200, 5150, 50-150 Mrad, 5-100, 5-50 , 5-40, 10-50, 10-75, 15-50, 20-35 Mrad.
[59] In some embodiments, relatively low doses of radiation are used, for example, to increase the molecular weight of a lignocellulosic or cellulosic material (with any radiation source or combination of sources described in this document). For example, a dose of at least approximately 0.05 Mrad, for example, at least approximately 0.1 Mrad or at least about 0.25, 0.5, 0.75. 1.0, 1.5, 2.0, 2.5, 3.0, 3.5, 4.0 or at least about 5.0 Mrad. In some embodiments, irradiation is performed until the material receives a dose of between 0.1 Mrad and 2.0 Mrad, for example, between 0.5 Mrad and 4.0 Mrad or between 1.0 Mrad and 3.0 Mrad.
[60] It may also be desirable to radiate from multiple directions,
26/83 simultaneously or sequentially, in order to achieve a desirable degree of radiation penetration into the material. For example, depending on the density and moisture content of the material, such as wood, and the type of radiation source used (for example, gamma rays or electron beam), the maximum radiation penetration into the material may be only about 0 , 75 inch. In such cases, a thicker section (up to 1.5 inches) can be irradiated by first irradiating the material on one side and then turning the material over and radiating on the other side. Multi-direction irradiation can be particularly useful with electron beam radiation, which radiates more quickly than gamma radiation, but typically does not reach a great depth of penetration.
MATERIALS OPAQUE TO RADIATION [61] The invention may include processing the material in a safe and / or shelter, which is constructed using materials opaque to radiation. In some implementations, radiation-opaque materials are selected to be able to protect components from x-rays with high energy (short wavelength), which can penetrate many materials. An important fact in the design of a radiation insulation compartment is the attenuation length of the materials used, which will determine the thickness required for a particular material, mix of materials, or layered structures. The attenuation length is the penetration distance over which the radiation is reduced by approximately 1 / e (e ~ Euler number) times that of the incident radiation. Although practically all materials are opaque to radiation since they are thick enough, materials containing a high compositional percentage (for example, density) of elements that have a high Z (atomic number) value have a shorter radiation attenuation length, and therefore, if such materials are used, thinner and lighter insulation is provided. Examples of materials with a high Z value that are used in radiation insulation are tantalum and lead. Another important parameter
27/83 in radiation isolation is the semi-reducing distance, which is the thickness required for a particular material to reduce the intensity of gamma rays by 50%. As an example of x-ray radiation with an energy of 0.1 MeV, the semi-reducing distance is about 15.1 mm for concrete, and about 0.27 mm for lead, while with ray energy ~ x, of 1 MeV, the semi-reducing distance of concrete is about 44.45 mm and for lead it is about 7.9 mm. Radiation-opaque materials can be materials that are thick or thin, as long as they can reduce the radiation that passes through the other side. Thus, if desired, a particular compartment may have a low wall thickness, for example, for light weight or due to size restrictions, the chosen material must have a sufficient Z value and / or attenuation distance so that its semi layer -reducer is smaller or equal to the desired wall thickness of the compartment.
[62] In some cases, the radiation-opaque material may be a layered material, for example, having a layer of a material with a higher Z value, to provide good shielding, and a layer of a material with a more Z low to provide other properties (eg structural integrity, impact resistance, etc.). In some cases, the layered material may be a Z-grade laminate, for example, including a laminate in which the layers provide a high Z gradation for successive low Z elements. In some cases, radiation-opaque materials can be interconnecting blocks, for example, lead and / or concrete can be supplied by NELCO Worldwire (Burlington, MA) and reconfigurable vault can be used as described in US Provisional Order No. 61 / 774,744.
[63] Radiation-opaque material can reduce radiation by passing through the structure (for example, a wall, door, ceiling, compartment, a series or combination of these) made up of a material of about 70% less (eg example, at least about 20%, at least
28/83 less than 30%, at least about 40%, at least about 50%, skin less than 60%, at least about 70%, at least about, at least about 80%, at least at least about 90%, at least about 95%, at least about 96%, at least about 97%, at least about 98%, at least about 99%, at least about 99.9%, at least about 99.99%, at least about 99.999%), compared to incident radiation. Therefore, a compartment made of radiation-opaque material can reduce the exposure of the equipment / system / component by the same amount. Materials opaque to radiation may include stainless steel, metals with Z values above 25 (for example, lead, iron), concrete, earth, sand and combinations thereof. Materials opaque to radiation may include a barrier in the direction of incident radiation of at least about 1 mm (for example, 5 mm, 10 mm, 5 cm, 10 cm, 100 cm, 1 m, 10 m).
RADIATION SOURCES [64] The type of radiation determines the types of radiation sources used, as well as the radiation devices and associated equipment. The methods, systems and equipment described in this document, for example, to treat materials with radiation, can use sources as described in this document, as well as any other useful source.
[65] Sources of gamma rays include radioactive nuclei, such as isotopes of cobalt, calcium, technetium, chromium, gallium, indium, iodine, iron, krypton, samarium, selenium, sodium, thallium and xenon.
[66] X-ray sources include electron beam collision with metal targets, such as tungsten or molybdenum or alloys, or compact light sources, such as those commercially produced by Lyncean.
[67] Alpha particles are identical to the nucleus of a helium atom and are produced by the alpha decline of several radioactive nuclei, such as
29/83 isotopes of bismuth, polonium, astatin, radon, francium, radium, various actinides, such as actinium, thorium, uranium, neptunium, curium. californium, americium, and plutonium.
[68] Sources of ultraviolet radiation include deuterium or cadmium lamps.
[69] Sources of infrared radiation include sapphire, zinc or selenide ceramic lamps.
[70] Microwave sources include clistrons, Slevin-type RF sources or atom beam sources that employ nitrogen, oxygen or hydrogen gases.
[71] Accelerators used to accelerate particles (for example, electrons or ions) can be electrostatic DC, DC electrodynamics, linear RF, linear magnetic induction or continuous wave. For example, various irradiation devices can be used in the methods disclosed in this document, including field ionization sources, electrostatic ion separators, field ionization generators, thermionic emission sources, microwave discharge ion sources, recirculation accelerators or static, dynamic linear accelerators, van de Graaff accelerators, Cockroft Walton accelerators (eg PELLETRON ® accelerators), LINACS, Dynamitrons (eg DYNAMITRON ® accelerators), cyclotrons, synchrotrons, betatrons, transformer type accelerators, microtrons , plasma generators, cascade accelerators and tandem folded accelerators. For example, cyclotron-type accelerators are available from IBA, Belgium, such as the RHODOTRON ™ system, while DC-type accelerators are available from RDI, now IBA Industrial, such as DYNAMITRON. Other suitable accelerator systems include, for example: DC insulated core transformer (ICT) systems, available from Nissín High Voltage, Japan; S-band UNACs, available through L3-PSD (USA),
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Linac Systems (France), Mevex (Canada), and Mitsubishi Heavy Industries (Japan); L-band LINACs, available through lotron Industries (Canada); and I LU-based accelerators, available through Budker Laboratories (Russia), ions and ion accelerators are discussed in Introductory Nuclear Physics, Kenneth S. Krane, John Wiley & Sons, Inc. (1988), Krsto Prelec, FIZIKA B 6 (1997) 4, 177-206; Chu, William T „Overview of Light-Ion Beam Therapy”, Columbus-Ohio, ICRU-IAEA Meeting, 18-20 March 2006; Iwata, Y. et aL, Alternating-Phase-Focused IHDTL for Heavy-Ion Medical Accelerators, Proceedings of EPAC 2006, Edinburgh, Scotland; and Leaner, CM. et al., Status of the Superconducting ECR Ion Source Venus ”, Proceedings of EPAC 2000, Vienna, Austria. Some particle accelerators and their uses are disclosed, for example, in Pat. US NT 7,931,784 to Medoff, the full disclosure of which is incorporated herein by reference.
[72] Electrons can be produced by radioactive nuclei that undergo beta decay, such as isotopes of iodine, technetium, cesium and iridium. Alternatively, an electron gun can be used as an electron source through thermionic emission and accelerated through an acceleration potential. An electron gun generates electrons, which are then accelerated through a large potential (for example, greater than approximately 500,000, greater than approximately 1 million, greater than approximately 2 million, greater than approximately 5 million, greater than approximately 6 million, greater than approximately 7 million, greater than approximately 8 million, greater than approximately 9 million, or even greater than 10 million volts) and then magnetically examined in the x ~ y plane, where electrons they are initially accelerated in the direction of the accelerator tube below and extracted through a blade window. Checking the electron beam is useful for increasing the irradiation surface when materials are irradiated, for example, a biomass, which is transmitted through the
31/83 beam examined. Checking the electron beam also distributes the thermal charge evenly on the window and helps to reduce the rupture of the blade window due to local heating by the electron beam. Blade window rupture is a cause of significant downtime due to subsequent necessary repairs and restart of the electron gun.
[73] An electron beam can be used as the radiation source. An electron beam has the advantages of high dose rates (for example, 1.5 or even 10 Mrad per second), high productivity, less containment, and less confinement equipment, electron beams can also have high electrical efficiency (for example, 80%), allowing lower energy usage compared to other radiation methods, which can translate into lower operating costs and lower greenhouse gas emissions corresponding to the lowest amount of energy used. Electron beams can be generated, for example, by electrostatic generators, cascade generators, transforming generators, low-energy accelerators with a scanning system, low-energy accelerators with a linear cathode, linear accelerators and pulsed accelerators.
[74] Electrons may also be more efficient by causing changes in the molecular structure of carbohydrate-containing materials, for example, by the chain's cleavage mechanism. In addition, electrons with: energies of 0.5-10 MeV can penetrate low density materials, such as the biomass materials described in this document, for example, materials having a mass density volume of less than 0.5 g / cm 3 and a depth of 0.3 to 10 cm. Electrons as a source of ionizing radiation can be useful, for example, for relatively thin cells, layers or beds of materials, for example, less than approximately 0.5 inches, for example less than approximately 0.4 inches, 0.3 inches , 0.25 inches or less than approximately 0.1 inches. In some embodiments, the energy of each electron in the
32/83 electron is about 0.3 MeV to about 2.0 MeV (million electron volts), for example, from about 0.5 MeV to about 1.5 MeV, or about 0, 7 MeV at about 1.25 MeV. Methods of irradiation of materials are discussed in Order of Pat US Pub. 2012/0100577 A1, filed on October 18, 2011, the full disclosure of which is incorporated herein by reference.
[75] Electron beam irradiation devices can be purchased commercially or built. For example, elements or components of such inductors, capacitors, capsules, power supplies, cables, wiring, voltage control systems, current control elements, insulation material, microcontrollers and refrigeration equipment can be purchased and mounted on a device . Optionally, a commercial device can be modified and / or adapted. For example, devices and components can be purchased from any of the commercial sources described in this document, including Ion Beam Applications (Louvain-la-Neuve, Belgium), NHV Corporation (Japan), Titan Corporation (San Diego, CA), Vivirad High Voltage Corp (BÍIIeric, MA) and; or Budker Laboratories (Russia) .. Typical electron energies can be 0.5 MeV, 1 MeV, 2 MeV, 4.5 MeV, 7.5 MeV or 10 MeV. Typical electron beam irradiation can be 1 kW, 5 kW, 10 kW, 20 kW, 50 kW, 60 kW, 70 kW, 80 kW, 90 kW, 100 kW, 125 kW, 150 kW, 175 kW, 200 kW , 250 kW, 300 kW, 350 KW, 400 kW, 450 kW, 500 kW, 600 kW, 700 kW, 800 kW, 900 kW or even 1000 kW. Accelerators that can be used include NHV radiators from the EPS-500 medium power series (eg, 500 kV voltage accelerators and 65, 100 or 150 mA beam current), EPS-800 (eg 800 kV voltage accelerator) and 65 or 100 mA beam current), or EPS-1000 (e.g., 1000 kV voltage accelerator and 65 or 100 mA beam current). In addition, NHV high-energy series accelerators can be used, such as EPS-1500 (for example,
33/83 voltage 1500 kV and 65 mA beam current), EPS-2000 (for example, 2000kV voltage accelerator and 50 mA beam current), EPS-3000 (for example, 3000 kV voltage accelerator and 50mA of beam current) and EPS-5000 (for example, 5000 and 30 mA beam current).
[76] Advantages and disadvantages when considering specifications for the power of the electron beam irradiation device Include cost to operate, capital costs, depreciation, and footprint (pollution) of the device. Implications in considering the dose levels of electron beam radiation exposure would be energy costs and environmental, safety and health (ESH) concerns. Typically, generators are housed in a chamber, for example, of lead or concrete, especially for the production of X-drains that are generated in the process, implications for considering electron energies include energy costs.
[77] The electron beam irradiation device can produce a fixed beam or a check beam. A scan beam can be advantageous with long scan scan length and high scan speed, as this would effectively replace a large fixed beam width. In addition, available sweep widths of 0.5 m, 1 m, 2 m or more are available. The check beam is preferred in most of the modalities described here because of the greater check width and reduced possibility of local heating and window failure.
ELECTRON CANNES - WINDOWS [78] The extraction system for an electron accelerator can include two window blades. Window slides are described in US Provisional Order No. Serial 61 / 711,801 filed on October 10, 2012, the full disclosure of which is incorporated into this document by reference. The refrigerant gas in the window extraction system of two
34/83 blades can be a purge gas or a mixture, for example air or a pure gas. In one embodiment, gas is an inert gas such as nitrogen, argon, helium and or carbon dioxide. It is preferable to use a gas instead of a liquid, as the energy losses to the electron beam are minimized. Pure gas mixtures can also be used, premixed or mixed in line before impacting on the window or in the space between the windows. Refrigerant gas can be cooled, for example, using a heat exchange system (for example, a cooling machine) and / or by boiling a condensed gas (for example, liquid nitrogen, liquid helium).
[79] When using a compartment, the closed conveyor can also be purged with an inert gas, in order to maintain an atmosphere at a reduced level of oxygen. Keeping oxygen levels low prevents the formation of ozone, which in some cases is undesirable due to its reactive and toxic nature. For example, oxygen can be less than approximately 20% (for example, less than approximately 10%. Less than approximately 1%, less than approximately 0.1%, less than approximately 0.01%, or even less than approximately 0.001% oxygen). Purge can be done with an inert gas, including but not limited to nitrogen, argon, helium or carbon dioxide. This can be provided, for example, from a boil from a liquid source (for example, nitrogen or liquid helium), generated or separated from in situ air or supplied from tanks. The inert gas can be recirculated and any residual oxygen can be removed using a catalyst, such as a copper catalyst bed. Alternatively, combinations of purge, recirculation and oxygen removal can be performed to keep oxygen levels low.
[80] The carrier compartment can also be purged with a reactive gas that can react with biomass. This can be done before, during or after the irradiation process. Reactive gas can be,
35/83 but not limited to, nitrous oxide, ammonia, oxygen, ozone, hydrocarbons, aromatic compounds, amides, peroxides, azides, halides, oxyhalides, phosphides, phosphines, arsines, sulfides, thiols, boranes and / or hydrides. The reactive gas can be activated in the carrier compartment, for example, by irradiation (for example, electron beam, UV irradiation, microwave irradiation, heating, IR radiation), so that it reacts with biomass. The biomass itself can be activated, for example, by irradiation. Preferably, the biomass is activated by the electron beam, to produce radicals which then react with the reactive gas activated or deactivated, for example, by coupling or removing the radical.
[81] Purge gases supplied to a closed conveyor can also be cooled, for example below about 25 * 0, below about O ^and C _s below approximately ~ 40®C, below about ~ 80 ^o C below about -120 ° C. For example, the gas can be boiled from a compressed gas such as liquid nitrogen or sublimated from solid carbon dioxide. As an alternative example, the gas can be cooled by a cooling machine or part or all of the conveyor can be cooled.
HEATING AND TRANSFER RATE DURING RADIATION TREATMENT [82] Various processes can occur in biomass when electrons from an electron beam interact with matter in inelastic collisions. For example, ionization of the material, polymer chain cleavage in the material, crosslinking of polymers in the material, oxidation of the material, generation of X-rays ('' Bremsstrahlung ”) and vibrational excitation of molecules (for example, phonon generation) . Without being bound by a particle mechanism, the reduction in recalcitrance may be due to the effects of these several of these inelastic collisions, for example, ionization, polymer chain cleavage, oxidation and phonon generation. Some of
36/83 effects (for example, especially the generation of X-rays), require shielding and engineering barriers, for example, enclosing the irradiation processes in a concrete vault (or other material opaque to radiation) Another effect of irradiation , the vibration excitation, is equivalent to heating the sample. Heating the sample by irradiation can help to reduce recalcitrance, but overheating can destroy the material, as explained below.
[83] The increase in adiabatic temperature (ΔΤ) from the absorption of ionizing radiation is given by the equation: ΔΤ ~ D / Cp: where D is the average dose in kGy, Cp is the heat capacity in J / g ° C, and ΔΤ is the temperature change in ° C. A typical dry biomass material will have a heat capacity close to 2. The wet biomass will have a higher heat capacity, depending on the amount of water, since the heat capacity of the water is very high (4.19 J / g ° C ). Metals have much lower heat capacities, for example, stainless steel 304 has a thermal capacity of 0.5 J / g ° C. The temperature change due to the instantaneous adsorption of radiation in a biomass and stainless steel for various radiation doses is shown in Table 1.
Table 1: Temperature Increase Calculated for biomass and stainless steel.
Dose (Mrad) Biomass Δ BioEstimated (° C) Steel ΔΤ (° C) Ϊ0 50 200 50 .................................... ['250 .......... .................................................. ............ So ........................................ 100 500 2000 15Õ 750 3000 200 1000 4000
[84] High temperatures can destroy and or mooify biopolymers in biomass, so that polymers (for example,
37/83 cellulose) are Unsuitable for further processing. Biomass subjected to high temperatures can become dark, sticky and generate odors that indicate decomposition. The viscosity even makes the material difficult to transport. Smells can be unpleasant and a safety issue. In fact, keeping the biomass below about 200 ° C has been found to be beneficial in the process described herein (e.g., below about 190 ° C, below about 180 ° C, below about 170 C , below about 160 ° C, below about 150 ° C, below about 140 ^σ 0, below about 130 ° C, below about 120 ° C, below about 110 ^ô C, between about 6Q ° C and 180 ° C _are between about 6Q ° C and 160 ° C, between about 60 ° C to 150 ° C, between about 60 ° C and 140 ° C, between about 60 ° C and 130 ° C, between about 60 ° C and 120 ° C, between about 80 ° C and 180 ^δ Ο, between about 100 ° C and 180 ° C, between about 120 ° C and 180 ^ô C, between about 140 ° C and 180 ° C. ⁸ between about 160 C and 180 C, between about 100 ° C and 140 ° C, between about 80 ° C to 120 ° C).
[85] It has been found that irradiation above about 10 Mrad is desirable for the processes described in this document (for example, reduction of recalcitrance). A high flow is also desirable, so that irradiation does not become a limiting factor in biomass processing. The treatment is managed by a dose rate equation: M ~ FP / D * time, where M is the mass of the irradiated material (Kg), F is the fraction of power that is adsorbed (without unit), P is the emitted power (kW ~ Voltage in MeV * Current in mA), time is the treatment time (sec) and D is the adsorbed dose (kGy). In an example process, where the adsorption power fraction is fixed, the emitted Power is constant and a fixed dosage is desirable, the flow rate (for example, M, the processed biomass) can be increased by increasing the irradiation time. However, increasing the irradiation time without allowing the material to cool can overheat the material, as exemplified by the calculations shown above. Since biomass has a low thermal conductivity (less
38/83 than about 0.1 Wm ^ K ' ¹ ) heat dissipation is slow, unlike, for example, metals (greater than about 10Wm ⁴ K ¹ ) that can dissipate energy quickly, as long as there is a heatsink to which energy can be transferred.
ELECTRON CANNONS - BEAM HYMATTERS [86] In some embodiments, systems and methods include a beam limiter (for example, a shutter). For example, the beam limiter can be used to quickly stop and reduce material irradiation without turning off the electron beam device. Alternatively, the beam limiter can be used while energizing the electron beam, for example, the beam limiter can stop the electron beam until a beam current of a desired level is achieved. The beam limiter can be placed between the primary blade window and the secondary blade window. For example, the beam limiter can be mounted so that it is movable, that is, so that it can be moved in and out of the beam path. Even a partial beam coverage can be used, for example, to control the radiation dose. The beam limiter can be mounted on the floor, on a biomass conveyor, on a wall, on the radiation device (for example, on the scanning device) or on any structural support. Preferably the beam limiter is fixed in relation to the check rod so that the beam can be effectively controlled with the beam limiter. The beam limiter can incorporate a hinge, a rail, wheels, grooves or other means, allowing its operation to move in and out of the beam. The beam limiter can be made of any material that will stop at least 5% of the electrons, for example, at least 10%, 20%, 30%, 40%, 50%, 60%, 70%, at least 80% , 85%, 90%, 91%, 92%, 93%, 94%, 95%, 96%, 97%, 98%, 99% or even approximately 100% of the electrons.
[87] The beam limiter can be made of a metal including, among
39/83 others, stainless steel, lead, iron, molybdenum, silver, gold, titanium, aluminum, tin or their alloys or laminates (layered materials) made with such metals (eg metal-coated ceramic, polymer-coated polymer) metal-coated compounds, multi-layered metal materials).
[88] The beam limiter can be cooled, for example, with a refrigerant such as an aqueous solution or a gas. The beam limiter can be partially or completely hollow, for example with cavities. Interior spaces of the beam limiter can be used for refrigerant fluids and gases. The beam limiter can be of any shape, including flat, curved, round, oval, square, rectangular, chamfered and probed.
[89] The beam limiter may have perforations in order to allow some electrons to pass, thereby controlling (for example, reducing) radiation levels in the entire window area, or in specific regions of the window. The beam limiter can be a mesh formed, for example, of fibers or yarns. Several beam limiters can be used, together or independently, to control irradiation. The beam limiter can be controlled remotely, for example, by radio signal or connected to a motor to move the beam in or out of position.
BEAM DEFLECTOR [90] The modalities disclosed in this document may also include a beam deflator. The function of a beam deflator is to safely absorb a beam of charged particles. Like a beam limiter, a beam deflator can be used to block the beam from charged particles. However, a beam deflator is much more robust than a beam limiter, and its intention is to block the full power of the electron beam for an extended period of time. They are often used to block the beam while the
40/83 accelerator is starting.
[91] Beam deflectors are also designed to accommodate the heat generated by such beams, and are normally made, and are usually made of materials such as copper, aluminum, carbon, beryllium, tungsten, or mercury. Beam deflectors can be cooled, for example, using a cooling fluid that is in thermal contact with the beam deflector.
BIOMASS MATERIALS [92] Lignocellulosic materials include, but are not limited to, wood, particle board, forest residues (eg sawdust, aspen wood, wood chips), grasses, (eg millet, miscanthus, spartina, yellow grass), grain residues (for example, rice husks, oat husks, wheat straw, barley husks), agricultural residues (for example, silage, canola straw, wheat straw, straw barley, oat straw, rice straw, jute, hemp, flax, bamboo, sisal, abaca, corn cobs, corn straw, soybean stems and leaves, corn fiber, aifafa, hay, coconut fiber), waste processed sugar (eg bagasse, beet pulp, agave bagasse), seaweed, seaweed, manure, sewage and mixtures of any of these.
[93] In some cases, lignocellulosic material includes ears of corn. Mashed corn cobs or mechanically molds can be spread in a layer of relatively uniform thickness for irradiation, and after irradiation they are easy to disperse in the medium for further processing. To facilitate harvesting and harvesting, in some cases the entire corn plant is used, including corn stalk, corn kernels, and in some cases, even the plant's root system.
[94] Advantageously, no additional nutrients (other than a source of nitrogen, for example, urea or ammonia) are needed during
41/83 fermentation of corn cobs or Igneous cellulosic or cellulosic materials containing significant amounts of corn cobs.
[95] Corn cobs, before and after comminution, are also easier to transport and disperse and are less likely to form explosive mixtures in the air than other cellulosic or lignocellulosic materials such as hay and grasses.
[96] Cellulosic materials include, for example, paper, paper products, waste paper, cellulose, pigmented papers, loaded papers, coated papers, filled papers, magazines, Printed matter (for example, books, catalogs, manuals, labels, calendars , postcards, brochures, prospectuses, newsprint), printer paper, multi-coated paper, cardboard, cardboard, cardboard, materials with a high cellulose content, such as cotton and mixtures of any of these. For example, paper products as described in U.S. Order No. 13 / 396,365 (Magazine Feedstocks ”by Medoff et al., Filed on February 14, 2012), the full disclosure of which is incorporated herein by reference.
[97] Cellulosic materials may also include lignocellulosic materials, which have been partially or completely smoothed.
[98] In some cases, other biomass materials may be used, for example, materials with starch. Starch-rich materials include starch itself, for example, corn starch, wheat starch, potato starch or rice starch, a starch derivative or a material that includes starch, such as an edible food product or a crop. For example, the starchy material can be cassava, buckwheat, banana, barley, manioc, cudzu, hollow, sago, sorghum, regular domestic potatoes, sweet potatoes, taro, yams or one or more beans, such as broad beans, lentils or peas . Mixtures of two or more starchy materials are also starchy materials. Mixtures of starchy, cellulosic and or lignocellulosic materials can also be used. Per
42/83 example, biomass can be an entire plant, a part of a plant or different parts of a plant, for example, a wheat plant, cotton plant, a corn plant, rice plant or a tree. Starch-rich materials can be treated by any of the methods described in this document.
[99] Microbial materials include, but are not limited to, any natural or genetically modified microorganisms or organisms that contain or are capable of providing a source of earbohydrates (eg, cellulose), eg, protists, eg, protist animals (for example, protozoa such as flagellates, amoeboids, ciliates and sporozoa) and protist plants (for example, algae such as honeycombs, chlorarachneas, cryptophytes, euglenofita, glaucophyita, haptophytas, red algae, stramenophila and viridiplantae). Other examples include algae, plankton (for example, macroplankton, mesoplankton, microplankton, plankton, plankton and femtoplankton [100]), phytoplankton, bacteria (for example, gram positive bacteria, gram-negative and extremophilic bacteria), yeast and / or mixtures of these. In some cases, microbial biomass can be obtained from natural sources, for example, the ocean, lakes, bodies of water, for example, salt water or fresh water, or on land. Alternatively, or in addition, microbial biomass can be obtained from culture systems, for example, large-scale dry and wet culture and fermentation systems.
[101] In other embodiments, biomass materials, such as cellulosic, starch-rich and lignocellulosic materials, can be obtained by transgenic microorganisms and plants that have been modified in relation to a wild type variety. Such modifications can be, for example, through the interactive steps of selection and cultivation to obtain desired characteristics in a plant. In addition, the plants may have had genetic material removed, modified, silenced or
43 / S3 added with respect to the wild type variety. For example, genetically modified plants can be produced by recombinant DNA methods, where genetic modifications include introducing or modifying specific genes of parental varieties, or, for example, using transgenic breeders in which a specific gene or genes are introduced to a plant. a different species of plant and / or bacteria. Another way to create genetic variation is through mutation reproduction in which new alleles are artificially created from endogenous genes. Artificial genes can be created in a variety of ways, including treating the plant or seeds with, for example, chemical mutagens (for example, using alkylating agents, epoxides, alkaloids, peroxides, formaldehydes), irradiation (for example, X, gamma rays, neutrons, beta particles, alpha particles, protons, deuterons, UV radiation) and temperature shock or other external voltage and subsequent selection techniques. Other methods of delivering modified genes is through error-prone PCR and DNA shuffling followed by insertion of the desired modified DNA into the desired plants or seeds. Methods of introducing the desired genetic variation into the seeds or plant include, for example, the use of a bacterial carrier, bio-statistics, calcium phosphate precipitation, electroporation, genetic splicing, genetic silencing, lipofection, microinjection and viral transporters. Additional genetically modified materials have been described in U.S. Order No. 13 / 396,369 filed February 14, 2012, the full disclosure of which is incorporated herein by reference.
[102] Any of the methods described in this document can be practiced with mixtures of any biomass materials described here.
OTHER MATERIALS
44/83 [103] Other materials (for example, natural or synthetic materials), polymers, for example, can be treated and / or made using the methods, equipment and systems described herein. For example, polyethylene (for example, linear low density ethylene and high density polyethylene), polyesters, sulfonated polyesters, poly (vinyl chloride), polyesters (for example, nylon stockings, Dacron ™, Kodel ™), esters polyalkylene, poly vinyl esters, polyamides (eg, Kevlar ™), polyethylene terephthalate, cellulose acetate, acetal, poly acrylonitrile, polycarbonates (Lexan ™), acrylics (eg, poly (methyl methacrylate), poly ( methyl methacrylate), polyacrylic nitric, polyurethanes, polypropylene, poly butadiene, polyisobutylene, polyacrylonitrile, polyhydropropene (eg neoprene), poly (cys-1,4-isoprene) [eg natural rubber], poly (trans ~ 1,4-isoprene) [eg gutta-percha], phenol formaldehyde, melamine formaldehyde, epoxides, polyesters, polyamines, polycarboxylic acids, polylactic acids, polyvinyl alcohols, polyanide, poly fluoro carbon (eg Teflon ™ ), siliconates (for example, silicone rubber), polysilanes, poly ethers (for example, polyethylene oxide, polypropylene oxide), waxes, oils and mixtures thereof. Also included are plastics, rubbers, elastomers, fibers, waxes, gels, oils, adhesives, thermopiastics, thermosets, biodegradable polymers, resins made with these polymers, other polymers, other materials and combinations thereof. Polymers can be made by any useful method, including cationic polymerization, anionic polymerization, radical polymerization, metathesis polymerization, ring opening polymerization, graft polymerization, addition polymerization. In some cases, the treatments disclosed in this document can be used, for example, for radically initiated graft polymerization and crosslinking. Polymer composites, for example, with glass, metals, biomass (for example, fibers, particles), ceramics can also be treated and / or made.
45/83 [104] Other materials that can be treated using the methods, systems and equipment disclosed in this document are ceramic materials, minerals, metals, inorganic compounds. For example, silicon and germanium crystals, silicon nitrides, metal oxides, semiconductors, insulators, cements and or conductors.
[105] Additionally, materials with various parts or shapes (for example, molded, extruded, welded, riveted, layered, or a combination in any way) can be treated, for example, cables, pipes, plates, compartments, integrated semiconductor chips, circuit boards, wires, tires, windows, laminated materials, gears, belts, machines, and combinations thereof. For example, treating a material with the methods described in this document, for example, you can modify the surfaces, for example example, making them susceptible to greater functionalization, combinations (eg welding) and / or cross-cutting can cross-link materials.
PREPARATION OF BIOMASS MATERIAL - MECHANICAL TREATMENTS [1Ô6] Biomass can be in dry form, for example, with less than approximately 35% moisture content (for example, less than approximately 20%, less than approximately 15%, less than approximately 10%, less than approximately 5%, less than approximately 4%, less than approximately 3%, less than approximately 2% or even less than approximately 1%). Biomass can also be delivered in a wet state, for example as a wet solid, a slurry or a suspension with at least 10% by weight of solids (for example, at least about 20% by weight, at least about 30% by weight at least approximately 40% by weight, at least approximately 50% by weight, at least approximately 60% by weight, at least
46/83 approximately 70% by weight), [1] The processes disclosed in this document may use materials of low apparent density, for example cellulosic or lignocellulosic raw materials that have been physically pretreated to have a bulk density of less than about 0.75 g / cm3, for example, which is about 0.7. 0.65, 0.60, 0.50, 0.35, 0.25, 0.20, 0.15, 0.10, 0.05 or less, for example, less than about 0.025 g / cm3. Bulk density is determined using ASTM D1895B. Briefly, the method involves filling a known volume measuring cylinder with a sample and obtaining a sample weight. Bulk density is calculated by dividing the sample weight in grams by the known volume of the cylinder in cubic centimeters. If desired, low density materials can be densified, for example, by the methods described in Pat. US M ⁰ 7,971,809 to Medoff, the full disclosure of which is incorporated herein by reference. In some cases, pre-treatment processing includes sorting the biomass material. Screening can be through a mesh or perforated plate with a desired opening size, for example, less than approximately 6.35 mm (1/4 inch, 0.25 inch), (for example, less than approximately 3, 18 mm (1/8 inch, 0.125 inch), less than approximately 1.59 mm (1/16 inch, 0.0625 inch), less than approximately 0.79 mm (1/32 inch, 0.03125 inch ), for example, less than approximately 0.51 mm (1/50 inches, 0.02000 inches), less than approximately 0.40 mm (1/64 inches, 0.015625 inches), less than approximately 0.23 mm (0.009 inches), less than approximately 0.20 mm (1/128 inches, 0.0078125 inches), less than approximately 0.18 mm (0.007 inches), less than approximately 0.13 mm (0.005 inches), or even less than approximately 0.10 mm (1/256 inches 0.00390625 inches)). In a configuration the desired biomass falls
47/83 through perforations or mesh and therefore the biomass larger than the perforations or mesh is not irradiated. These larger materials can be reprocessed, for example, by commuting, or simply removed from processing. In another configuration, the material that is larger than the perforations is irradiated and the smallest material is removed by the process of sorting or recycling. In this type of configuration, the conveyor itself (for example, a part of the conveyor) can be perforated or made with a mesh. For example, in a particular embodiment, the biomass material can be wetted and the perforations or mesh allow water to drain from the biomass before irradiation.
[2] Material screening can also be done by a manual method, for example, by an operator or robot (for example, a robot equipped with a color, reflectivity or other sensor) that removes unwanted material. The sorting can also be by magnetic sorting, in which a magnet is placed close to the transported material and the magnetic material is removed magnetically.
[3] Optional pretreatment processing may include heating the material. For example, a part of the carrier can be sent through the heated zone. The heated zone can be created, for example, by IR radiation, microwave, combustion (for example, gas, coal, oil, biomass), resistive heating and / or inductive coils. Heat can be applied from at least one or more to one side, it can be continuous or periodic and it can be only to a part of the material or the whole material. For example, a portion of the conveyor can be heated by using a heating liner. The heating can be, for example, for the purpose of drying the material. In the case of drying of the material, this can also be facilitated, with or without heating, by the movement of a gas (for example, air, oxygen, nitrogen, He, CO2, argon) over and / or through the biomass, when it is being transported.
48/83 [4] Optional pretreatment processing may include cooling the material The cooling material is described in Pat. US No. 7,900,857 to Medoff, the full disclosure of which is incorporated by reference here. For example, cooling can be through the supply of a cooling fluid, for example water (for example, with glycerol) or nitrogen (for example, liquid nitrogen) to the bottom of the transport tank. Alternatively, a cooling gas, for example, refrigerated nitrogen, can be applied over biomass materials or under the transport system.
[5] Another optional pre-treatment processing method may include adding a material to the biomass. The additional material can be added, for example, by showering, dusting and / or by pouring the material over the biomass, as it is transported. Materials that can be added include, for example, metals, ceramics and / or sounds as described in U.S. Pat. U.S. US Pub. 2010/0105119 A1 (filed October 26, 2009) and Pat. U.S. US Pub. 2010/0159569 Al (filed December 16, 2009), the full disclosures of which are incorporated herein by reference. Optional materials that can be added include acids and bases. Other materials that can be added are oxidizers (eg, peroxides, chlorates), polymers, polymerizable monomers (eg, containing unsaturated bonds), water, catalysts, enzymes and / or organisms. Materials can be added, for example, in pure form, as a solution in a solvent (for example, water or an organic solvent) and / or as a solution. In some cases, the solvent is volatile and can be made by evaporation, for example, by heating and / or blowing the gas as described above. The added material can form a uniform coating on the biomass or be a homogeneous mixture of different components (for example, biomass and additional material). The added material can modulate the subsequent irradiation step, increasing the irradiation efficiency,
49/83 dampening irradiation or changing the effect of irradiation (for example, from electron beams to ~ x-rays or heat). The method may have no impact on irradiation, but it can be useful for further downstream processing. The added material can help transport the material, for example, by decreasing dust levels.
[6] The biomass can be delivered to the conveyor (for example, vibrating conveyors that can be used on the vaults described in this document) by a conveyor belt, a pneumatic conveyor, a screw conveyor, a funnel, a pipe, manually or by a combination of these. The biomass can, for example, be dropped, poured and / or placed on the conveyor by any of these methods. In some embodiments, material is delivered to the conveyor using an embedded material distribution system to help maintain a low oxygen atmosphere and / or control dust and fines. Fine particles and biomass dust suspended in the air or elevated are undesirable, as they can pose a risk of explosion or damage the protective films of an electron gun (if such a device is used to treat the material).
[7] The material can be redistributed to form a uniform thickness between about 0.0312 and 5 inches (for example, between about 0.0625 and 2,000 inches, between 0.125 and 1 inch, between about 0.125 and 0.5 inches, between about 0.3 and 0.9 inches, between about 0.2 and 0.5 inches between about 0.25 and 1.0 inches, between about 0.25 and 0.5 inches.
[8] In general, it is preferable to transport the material as quickly as possible through the electron beam to maximize flow. For example, material can be transported at rates of at least 1 foot / min, for example, at least 2 feet / min, at least 3 feet / min, at least 4 feet / min, at least 5 feet / min, at least 10 feet / min, at least 15
50/83 feet / min, 20, 25, 30, 35, 40, 45, 50 feet / min. The transmission rate is related to the beam current, for example, for a biomass of% inch thick and 100 mA, the carrier can move at about 20 feet / min to provide a useful radiation dose, at 50 mA , the carrier can move at approximately 10 feet / min to provide approximately the same radiation dose, [9] After the biomass material has been transported through the radiation zone, optional post-treatment processing can be done. Optional post-treatment processing can, for example, be a process described in relation to pre-irradiation processing. For example, biomass can be screened, heated, cooled, or combined with additives. Exclusively for post-irradiation, the quenching of radicals can occur, for example, quenching of radicals by the addition of fluids or gases (eg, oxygen, nitrous oxide, ammonia, liquids), using pressure, heat, and / or the addition of radical remover. For example, biomass can be transported out of the built-in conveyor and exposed to a gas (for example, oxygen) where it is cooled, forming carboxylated groups. In one embodiment, biomass is exposed during irradiation to reactive gas or fluid. The quenching of the biomass that has been irradiated is described in Pat, US No. 8,083,906 to Medoff, whose full disclosure is incorporated by reference here.
[10] If desired, one or more mechanical treatments can be used in addition to irradiation to further reduce the recalcitrance of the carbohydrate-containing material. These processes can be applied before, during or after irradiation.
[11] In some cases, mechanical treatment may include an initial preparation of raw material as received, for example, size reduction of materials, such as by comminution, for example, cutting, shearing, spraying or chipping. For example, in some cases,
51/83 loose raw material (eg recycled paper, materials rich in starch, or millet) is prepared by shearing or shredding. Mechanical treatment can reduce the apparent density of the carbohydrate-containing material, increase the surface area of the carbohydrate-containing material and / or decrease one or more dimensions of the carbohydrate-containing material.
[12] Alternatively, or additionally, the raw material material can be treated with another treatment, for example, chemical treatments, such as with an acid (HCI, H ₂ SO ₄ , H ₃ PO ₄ ), a base (for example, KOH and NaOH), a chemical oxide (for example, peroxides, chlorides, ozone), irradiation, vapor explosion, pyrolysis, sonication, oxidation, chemical treatment. Q treatment can be in any order and in any sequence and combinations. For example, the raw material material can first be physically treated by one or more treatment methods, for example, chemical treatments including and in combination with acid hydrolysis (for example, using HCI, H ₂ SO ₄ , H ₃ PO ₄ ), radiation, sonication, oxidation and pyrolysis or steam explosion and then mechanically treated. This sequence can be advantageous, since the materials treated by one or more of the other treatments, for example, irradiation or pyrolysis, tend to be more fragile and, therefore, they can be easier to change the structure of the material by mechanical treatment. For example, a raw material can be transported by ionizing radiation using a carrier as described in this document and then treated mechanically. Chemical treatment can remove some or all of the lignin (for example chemical pulping) and can hydrolyze the material partially or completely. The methods can also be used with previously hydrolyzed material. The methods can also be used with material that has not been prehydraulic. The methods can be used with mixtures of hydrolyzed and non-hydrolyzed materials, for example, with about 50% or more non-hydrolyzed material, with about 60% or more non-hydrolyzed material, with about 70% cu
52/83 more of non-hydrolyzed material, with about 80% or more of non-hydrolyzed material or even with 90% or more of non-hydrolyzed material.
[13] In addition to size reduction, which can be performed initially and / or later in processing, mechanical treatment can also be advantageous to open it, ”'' tension, break or destroy materials containing carbohydrates, making cellulose of the materials most susceptible to chain splitting and / or rupture of the crystalline structure during physical treatment.
[14] Methods for mechanically treating carbohydrate-containing material include, for example, crushing or grinding. Milling can be carried out using, for example, a hammer mill, ball mill, cploidai mill, conical or cone mill, disc mill, Chilean mill, Wiley mill, cereal mill or other mill. The grinding can be carried out using, for example, a cut / impact type grinder. Some exemplary grinders include stone crushers, pin grinders, coffee grinders and drill grinders. The grinding or grinding can be provided, for example, by a reciprocating pin or other element, as is the case in a pin mill. Other methods of mechanical treatment include mechanical rupture, other methods that apply pressure to the fibers and crushing of air friction. Appropriate mechanical treatments include any other technique that continues to disrupt the internal structure of the material that was initiated by the previous processing steps.
[15] Mechanical feed preparation systems can be configured to produce flows with specific characteristics such as, for example, specific maximum sizes, specific length and width or specific surface area ratios. Physical preparation can increase the rate of reactions, improve the circulation of material
53/83 in a conveyor, improve the irradiation profile of the material, improve the uniformity of the radiation of the material or reduce the processing time required by opening the materials and making them more accessible for processes and / or reagents, such as reagents in a solution.
[1δ] The bulk density of raw materials can be controlled (for example, increased). In some situations, it may be desirable to prepare a low apparent density material, for example, by densifying the material (for example, densification can make it easier and less expensive to transport elsewhere) and then revert the material to a lower apparent density state (for example, after transport). The material can be densified, for example, from less than approximately 0.2 g / cc, to more than approximately 0.9 g / cc (for example, less than approximately 0.3 to more than approximately 0.5 g / cc cc, less than approximately 0.3 to more than approximately 0.9 g / cc, less than approximately 0.5 to more than approximately 0.9 g / cc, less than approximately 0.3 to more than approximately 0.3 g / cc, less than approximately 0.2 to more than approximately 0.5 g / cc). For example, the material can be densified by the methods and equipment disclosed in US Pat. 7,932,065 to Medoff and N ^ô International WO 2008/073186 publication (which was filed on October 26, 2007, was published in English, and designating the United States), whose entire disclosures are incorporated herein by reference. Densified materials can be processed by any of the methods described in this document, or any material processed by any of the methods described in this document can be further densified.
[17] In some embodiments, the material to be processed is in the form of a fibrous material that includes fibers provided by shearing from a fiber source. For example, shearing can be carried out with a rotary cutter.
54/83 [18] For example, a fiber source, for example, that is recalcitrant © or that has had its level of recateitrance reduced, can be shredded, for example, in a rotary cutter, to provide a first fibrous material. The first fibrous material is passed through a first screen, for example, with an average opening size of 1.59 mm or less (1/16 inch, 0.0625 inch), providing a second fibrous material. If desired, the fiber source can be cut before shearing, for example, with a shredder. For example, when a paper is used as the fiber source, the paper can first be cut into strips measuring, for example, 1/4 to 1/2 inch wide, using a shredder, for example, a shredder counter-rotation screw, such as those manufactured by Munson (Utica, NY). As an alternative to shredding, the paper can be reduced in size by cutting to a desired size using a guillotine cutter. For example, the guillotine cutter can be used to cut paper into sheets that are, for example, 10 inches wide by 12 inches long.
[19] In some embodiments, the shearing of the fiber source and the passage of the first resulting fibrous material through a first screen are performed simultaneously. Shearing and passing can also be carried out in a batch-type process.
[20] For example, a rotary cutter can be used to simultaneously shear the fiber source and protect the first fibrous material. A rotary cutter includes a funnel that can be loaded with a shredded fiber source prepared by shredding a fiber source.
[21] In some implementations, the raw material is physically treated before saccharification and / or fermentation. Physical treatment processes may include one or more of any of those described in this document, such as mechanical treatment, treatment
55/83 chemical, irradiation, sonication, oxidation, plolysis or steam explosion. Treatment methods can be used in combinations of two, three, four or even all of these technologies (in any order). When more than one treatment method is used, the methods can be applied simultaneously or at different times. Other processes that alter the molecular structure of the biomass raw material can also be used, alone or in combination with the processes disclosed in this document.
[22] Mechanical treatments that can be used and the characteristics of mechanically treated carbohydrate containing materials are described in more detail in Pat. US Pub. 2012/0100577 A1, filed on October 18, 2011, the entire disclosure of which is incorporated herein by reference.
SONICATION, PYROLYSIS, OXIDATION, VAPOR EXPLOSION [23] If desired, one or more processes of sonication, pyrolysis, oxidants or vapor explosion can be used in addition to or in lieu of irradiation to reduce or additionally reduce the relapse of the material containing carbohydrate. For example, these processes can be applied before, during or after irradiation. These processes are described in detail in Pat. US. No. 7,932,065 to Medoff, whose full disclosure is incorporated by reference in this document.
USE OF TREATED BIOMASS MATERIAL [24] Using the methods described in this document, a raw material from the initial biomass (eg plant biomass, animal biomass, paper and municipal biomass residues) can be used as a raw material for the production of useful intermediates and products, such as organic acids, salts of organic acids, anhydrides, esters of organic acids and fuels, eg motor fuels
56/83 internal combustion or raw materials for fuel cells. Systems and processes are described in this document which can use readily available cellulosic and / or IgG-cellulose materials as raw material, but can often be difficult to process, for example, municipal waste streams and waste paper streams, such as streams that include newspaper, pape! kraft, corrugated paper or mixtures thereof.
[25] In order to convert the raw material into a form that can be easily processed, cellulose containing glucan or xylan in the raw material can be hydrolyzed to low molecular weight carbohydrates, such as sugars, by a saccharifying agent, for example. example, an enzyme or acid, a process known as saccharification. Low molecular weight carbohydrates can then be used, for example, in an existing manufacturing plant, such as a single cell protein plant, an enzyme manufacturing plant, or a fuel plant, for example, a fuel plant. ethanol manufacturing [26] The raw material can be hydrolyzed using an enzyme, for example, by combining the materials and the enzyme in a solvent, for example, in an aqueous solution.
[27] As an alternative, enzymes can be supplied by organisms that break down biomass, such as cellulose and / or the portions of biomass iignin, contain or manufacture various cellulosic enzymes (cellulases), ligninases or various molecule biomass degrading metabolites small. These enzymes can be a complex of enzymes that act synergistically to degrade crystalline cellulose or the lignin portions of biomass. Examples of cellulotic enzymes: endoglucanases, cellobiohydrolases and cellobiases (beta-glucosidases).
[28] During saccharification, a cellulosic substrate can be initially hydrolyzed by endoglucanases at random locations,
57/83 producing oligomeric intermediates These intermediates are then substrates for exo - dividing glucanases such as cellobiohydrolase to produce cellobiosis from the ends of the cellulose polymer. Cellobiose is a dimer with 1,4 water-soluble glucose bonds. Finally, celobia and olive cellobiosis to produce glucose. The efficiency (eg, time to water and / or hydrolysis completeness) of this process varies according to the recalcitrance of the cellulosic material.
INTERMEDIARIES AND PRODUCTS [29] Using the processes described in this document, the biomass material can be converted into one or more products, such as energy, fuels, food and materials. Specific examples of products include, but are not limited to, hydrogen, sugars (eg, glucose, xylose, arabinose, mannose, galactose, fructose, disaccharides, oligosaccharides and polysaccharides), alcohols (for example, monoalcohols or alcohols dihydrides, such as ethanol, n-propanol, isobutanol, sec-butanol, tert-butanol or n-butanol), hydrated or water alcohols (for example, containing more than 10%, 20%, 30% or even more than 40% water), biodiesel, organic acids, hydrocarbons (for example, methane, ethane, propane, isobutene, pentane, hexane, biodiesel, bio-gasoline and mixtures thereof), co-products (for example, , proteins, such as cellulosic proteins (enzymes) or single cell proteins) and mixtures of any of these in any combination or relative concentration and, optionally, in combination with any additives (e.g., fuel additives). Other examples include carboxylic acids, salts of a carboxylic acid, a mixture of carboxylic acids and salts of carboxylic acids and esters of carboxylic acids (eg, methyl, ethyl and n-propyl esters), ketones (eg ,, acetone), aideides (e.g., acetaldehyde), alpha and beta unsaturated acids (e.g., acrylic acid) and olefins (e.g., ethylene). Other alcohols and alcohol derivatives include propanol, propylene glycol, 1,4-butanediol, 1,3-propanediol,
58/83 sugar alcohols and polyols (for example, gOcol, glycerol, erythritol, treitol, arabitol, xylitol, ribitol, mannitol, sorbitol, galactitol, iditol, inositol, volemitol, isomalt, maltitol, lactitol, maltotriitol, maltotriitol and maltotriitol, maltotriitol and maltotriitol and maltotriitol and and other polyols) and methyl or ethyl esters of any of these alcohols. Other products include methyl acrylate, methyl methacrylate, lactic acid, citric acid, formic acid, acetic acid, propionic acid, butyric acid, succinic acid, valeric acid, capric acid, 3-hydroxypropionic acid, palmitic acid, stearic acid, oxalic acid, malonic acid, gutaric acid, oleic acid, linoleic acid, glycolic acid, gamma-hydroxybutyric acid and mixtures thereof, salts of any of these acids, mixtures of any of the acids and their respective salts.
[30] Any combination of the above products with each other, and / or the above products with other products, the other products of which can be made by the processes described in this document or otherwise, can be packaged together and sold as products. Products can be combined, for example, mixed, combined or codissolved, or they can simply be packaged or sold together.
[31] Any of the products or product combinations described in this document can be hygienized or sterilized before the products are sold, for example, after purification or isolation or even after packaging, to neutralize one or more potentially unwanted contaminants that may be present. on the product (s). Such sanitation can be done with electron bombardment, for example, being at a dosage of less than approximately 20 Mrad, for example, approximately 0.1 to 15 Mrad, approximately 0.5 to 7 Mrad, or approximately 1 to 3 Mrad.
[32] The processes described in this document can produce several by-product streams useful for generating steam and electricity to be used.
59/83 used in other parts of the plant (cogeneration) or sold on the open market. For example, the steam generated from burning by-product streams can be used in a distillation process. As another example, the electricity generated from burning by-product streams can be used to power electron beam generators used in the pre-treatment.
[33] The by-products used to generate steam and electricity are derived from a number of sources throughout the process. For example, anaerobic digestion of wastewater can produce biogas with a high methane content and a small amount of residual biomass (sludge). As another example, post-saccharification and / or post-distillate solids (eg, unconverted lignin, cellulose, and hemicellulose remaining from the pretreatment and primary processes) can be used, for example, burned, as a fuel.
[34] Other intermediates and products, including food and pharmaceutical products, are described in Pat. US Pub. 2010/0124583 Al, published on May 20, 2010, the complete disclosure of which is incorporated by reference here.
LIGNIN DERIVED PRODUCTS [35] The irradiated biomass (eg spent lignocellulosic material) from Hgnocellulosic processing by the methods described is expected to have a high lignin content and, in addition to being useful for the production of energy through combustion in a Cogeneration plant, can have uses like other valuable products. For example, lignin can be used as captured as a plastic, or it can be synthetically enhanced for other plastics. In some cases, it can also be converted into lignosulfonates, which can be used as binders, dispersants, emulsifiers or as sequestrants.
[36] When used as an igniter, lignin or a lignosulfonate can, for example, be used in charcoal briquettes, ceramics, for
60/83 connection of carbon black, for connection of fertilizers and herbicides, as a dust suppressant, in the manufacture of plywood board and particleboard, for connection of animal feeds, as a gloss for fiberglass, oomo a liquid in the linoleum paste and as a soil stabilizer.
[37] As a dispersant, lignin or lignosulfonates can be used, for example, mixtures of concrete, clay and ceramics, dyes and pigments, leather tanning and plasterboard.
[3S] As an emulsifier, lignin or lignosulfonates can be used, for example, in asphalt emulsions, pigments and dyes, pesticides and wax.
[39] As a sequester, lignin or lignosulfonates can be used, for example, in mlcronutrient systems, cleaning compounds and water treatment systems, for example, for boiler and cooling systems.
[40] For energy production, lignin generally has a higher energy content than holocellulose (cellulose and hemicellulose), since it contains more carbon than holocellulose. For example, dry lignin can have an energy content between about 11,000 and 12,500 BTU per pound, compared to 7,000 to 8,000 BTU per pound of holocellulose. As such, lignin can be densified and converted into briquettes and petetes for burning. For example, lignin can be converted to pellets by any method described in this document. For a slower-firing pellet or briquette, the iignin can be cross-linked, such as applying a radiation dose of between about 0.5 Mrad and 5 Mrad. Crosslinking can become a slower burning form factor. The form factor, such as a pellet or briquette, can be converted to “synthetic charcoal” or charcoal by pyrolysis in the absence of air, for example, between 400 and 950 ^and C ^o . Before pyrolysis, it may be desirable to cross-link lignin to maintain
61/83 structural integrity.
[41] Cogeneration using irradiated biomass is described in US Provisional Application No. 61 / 774,773 whose full disclosure is hereby incorporated by reference.
BIOMASS PROCESSING AFTER RADIATION [42] After irradiation, the biomass can be transferred to a container for saccharification. Alternatively, the biomass can be heated after the biomass is irradiated, before a saccharification step. The biomass can be, for example, by IR radiation, microwave, combustion (for example, gas, coal, oil, biomass), heating resistive and / or inductive coils. This heating can be in a liquid, for example, in water or other water-based solvents. Heat can be applied from at least one or more to one side, it can be continuous or periodic and it can be only to a part of the material or the whole material. The biomass may be heated to temperatures above about 90 ^& C an aqueous liquid which can be an acid or base present. For example, the aqueous biomass slurry can be heated to 90 to 150 ^° C, alternatively 105-145 X, optionally 110 to 140 ° C or more optionally from 115 to 135 ° C. The time that the aqueous biomass mixture is maintained at the peak temperature is 1 to 12 hours, alternately 1 to 6 hours, optionally, 1 to 4 hours at the peak temperature. In some cases, the aqueous biomass mixture is acidic and the pH is between 1 and 5, optionally 1 to 4 or alternately, 2 to 3. In other cases, the aqueous biomass mixture is alkaline, and its pH is between 6 and 13 alternatively 8-12, or optionally 8-11.
SACARIRCAÇÂO [43] The treated biomass materials can be saccharified, usually by combining the material and a cellulase enzyme in a fluid medium, for example, an aqueous solution. In some cases, the material is
62/83 boiled, dipped or cooked in hot water before saccharification, as described in the Order of Pat, US Pub, 2012/0100577 A1 by Medoff and Masterman, filed on April 26, 2012, the entire contents of which are incorporated by reference , [44] The saccharification process can be partially or completely carried out in a tank (for example, a tank with a volume of at least 4000.40.000, or 500.000 L) in a manufacturing plant, and / or it can be partial or completely carried out in transit, for example, in a wagon, tanker truck, or a supertanker or in the hold of a ship. The time required for complete saccharification will depend on the process conditions and the material containing carbohydrate and enzyme used. If saccharification is carried out in a manufacturing plant under controlled conditions, cellulose can be substantially and entirely converted to sugar, for example glucose, in approximately 12-96 hours. If saccharification is performed partially or completely in transit, saccharification may take longer.
[45] It is generally preferred that the contents of the tank be mixed during saccharification, for example, using a mixing jet as described in International Order No. ⁰ PCT / US2010 / 035331, deposited on May 18, 2010, which was published in English as WO 2010/135380 and designated in the United States, the complete disclosure of which is incorporated by reference in this document.
[46] The addition of surfactants can increase the saccharification rate. Examples of nonionic surfactant surfactants, such as a Tween® 20 or Tween® 80 polyethylene glycol surfactants, tonic surfactants or amphoteric surfactants, [47] are generally preferred if the concentration of the sugar solution resulting from saccharification is relatively high, for example, greater than 40%, or greater than 50, 60, 70, 80, 90 or even greater than 95% per
63/83 weight. Water can be removed, for example, through evaporation, to increase the concentration of the sugar solution. This reduces the volume to be sent and also inhibits microbial growth in the solution.
[48] Alternatively, low-concentration sugar solutions can be used, if it is desirable to add an antimicrobial additive, for example, a broad spectrum antibiotic, in a low concentration, for example, 50 to 150 ppm. Other suitable antibiotics include amphotericin B, ampicillin, chloramphenicol, ciprofloxacin, gentamicin, hygromycin B. kanamycin, neomycin, penicillin, puromycin, streptomycin. Antibiotics inhibit the growth of microorganisms during transport and storage and can be used in suitable concentrations, for example, between 15 and 1,000 ppm by weight, for example, between 25 and 500 ppm or between 50 and 150 ppm. If desired, an antibiotic can be included, even if the sugar concentration is relatively high. Alternatively, other anti-microbial additives with preservative properties can be used. Preferably the antimicrobial additive (s) are food grade.
[49] A solution of relatively high concentration can be obtained by limiting the amount of water added to the biomass material with the enzyme. The concentration can be controlled, for example, by controlling how much saccharification occurs. For example, the concentration can be increased by adding more matter! containing carbohydrate for the solution, In order to keep the sugar being produced in solution, a surfactant can be added, for example, one of those discussed above, Solubility can also be increased by increasing the temperature of the solution. For example, the solution may be maintained at a temperature of 40 ~ ^oO 50 C, 60 ~ 80 ° C or even higher.
SACARIFICATION AGENTS [50] Suitable cellulosic enzymes include celluloses of species
64/83 in the genera Bacillus, Coprinus, Myce / iophthora, Cephafosporium, Scyta / idium, Pen / c / Hium, Aspergillus, Pseudomonas, Humico / a, Fusarium, Thie / avia, Acremonium, Chrysosporium and Tr / choderma, especially those produced by a strain selected from the Aspergillus species (see, for example, for example, EP Pub. No. 0 458 162), Hum / cola fnso / ens (reclassified as Scytal / dium thennoph / um, see, for example US Patent No. 4,435,307), Coprinus cinereus ,, Fusarium oxysporam, Myce /ophthora thermophi / a, Merípi / us giganteus, Thielavia temesms, Acremonium sp. (including, but not limited to, A. persicinum, A. acremonium, A. brachypeníum, Ádlcrirumosporum, A. obcíavatum, A. pinkertoniae, A. roseogriseum, A.incõloratum, and A. furatum). Preferred strains include Humioola mso / ens DSM 1800, Fusarium oxysporum DSM 2672, Myceliophthora thermophile CBS 117.65, Cephatosporium sp. RYM-202, Acremonium sp. CBS 478.94, Acremonium sp. CBS 265.95, Acremonium pers / cinum CBS 169.65, Acremonium acmmoniam AHU 9519, Cephalosporium sp. 535.71 C8S, Acremonium brachypeníam CBS 866.73, Acremonium dichromosporum CBS 683.73, Acremonium obc / avato CBS 311.74, Acremonium pinkertoniae CBS 157.70, Acremoníumroseogriseum CBS 134.56, Acremonium incoloratum CBS 146.6.H. Celuotic enzymes can also be obtained from Chrysosporium, preferably a lucknowense strain of Chrysosporium. Additional strains that can be used include, but are not limited to, Trichoderma (particularly T. vinde, T. reesei, and T. kon / ηρΠ), alkalophilic Bacfes (see, for example, Pat.US No. 3,844,890 and EP Pub. No. 0 458 162) and Streptomyces (see, for example, EP Pub. No. 0 458 162).
[51] In addition to or in combination with enzymes, acids, bases and other chemicals (eg oxidizers), they can be used to saccharify cellulosic or lignocellulosic material. These can be used in any combination or sequence (for example, before, after and / or during the addition of an enzyme). For example, strong mineral acids
65/83 can be used (eg.HCI, H ₂ SO ₄ , H PO ₄ ) and strong bases (eg NaOH, KOH).,
SUGARS [52] In the processes described in this document, for example after saccharification, sugars (eg, glucose and xylose) can be isolated. For example, sugars can be isolated by precipitation, crystallization, chromatography (eg., Simulated moving chromatography, high pressure chromatography), centrifugation, extraction, any other isolation method known in the art and combinations thereof.
HYDROGENATION AND TRANSFORMATION OF OTHER CHEMICALS [53] The processes described in this document may include hydrogenation. For example, glucose and xylose can be hydrogenated to sorbitol and xiiitol, respectively. Hydrogenation can be carried out by using a catalyst (for example, Pt / gamma-A1 ₂ O3. Ru / C, Raney Nickel or other catalysts known in the art) in combination with H ₂ under high pressure (for example / o , 10 to 12000 psi). Other types of chemical transformation of products from the processes described in this document can be used, for example, production of products derived from organic sugar (for example, furfural and furfural derivatives). Chemical transformations of sugar-derived products are described in Patent Application No. 13/934704, filed on July 3, 2013, the disclosure of which is hereby incorporated by reference, in its entirety.
FERMENTATION [54] Yeast and bacteria Zymomonas, for example, can be used for fermentation or conversion of sugar to alcohol (ois). Other microorganisms are discussed below. The ideal pH for fermentation is
66/83 around pH 4 to 7. For example, the ideal pH for yeast is around pH 4 to 5, while the ideal pH for Zymomonas bacteria is around pH 5 to 6. Typical fermentation times are around 24 to 168 hours (for example, 24 to 96 hours.) Typical fermentation times are approximately 20 ° C to 40 * C (for example, 26 * 0 to 40 ^c C), however termaphilic microorganisms prefer higher temperatures.
[55] In some embodiments, for example, when anaerobic organisms are used, at least part of the fermentation is conducted in the absence of oxygen, for example, under a blanket of an inert gas such as N2, Ar, He, CO2 or their mixtures. In addition, the mixture may have a constant purge of an inert gas flowing through the tank during part or all of the fermentation. In some cases, the anaerobic condition can be achieved or maintained by the production of carbon dioxide during fermentation and no additional inert gas is required.
[56] In some embodiments, all or part of the fermentation process can be stopped before low molecular weight sugar is completely converted into a product (eg, ethanol). Intermediate fermentation products include sugar and carbohydrates in high concentrations. Sugars and carbohydrates can be isolated by any means known in the art. These intermediate fermentation products can be used in the preparation of food for human or animal consumption. In addition or, alternatively, intermediate fermentation products can be ground to fine particle size in a stainless steel laboratory mill to produce a floury substance. Jet mixing can be used during fermentation, and in some cases saccharification and fermentation are performed in the same tank.
[57] Nutrients for microorganisms can be added during saccharification and / or fermentation, for example,
67/83 food-based nutrients described in the US Pub Patent Application. No. 2012/0052536, filed on July 15, 2011, the full disclosure of which is incorporated by reference here.
[58] Fermentation includes the methods and products that are disclosed in WO 2013/096700, filed on December 22, 2012, and Order US NP PC17US2012 / 071083, filed on December 22, 2012, the contents of which are both incorporated by reference in this document in its entirety.
[58] Mobile fermenters can be used, as described in International Application No. ⁰ PCT / US2007 / 074028 (which was filed on July 20, 2007, was published in English as WO 2008/011598 and designated United States) and which has patent number No. 8,318,453, issued in the United States, the content of which is incorporated herein in its entirety. Similarly, saccharification equipment can be mobile. In addition, saccharification and / or fermentation can be carried out in part or totally during transit.
FERMENTATION AGENTS [60] The microorganism (s) used in the fermentation can be naturally occurring microorganisms and / or engineering microorganisms. For example, the microorganism can be a bacterium (including, but not limited to, for example, cellulotic bacteria), a fungus, (including, but not limited to, for example, a yeast), a plant, a protist, for example example, a fungus-like protozoan or protist (including, but not limited to, for example, a lime mold) or algae. When the organisms are compatible, mixtures of organisms can be used.
[61] Proper fermentation of microorganisms has the ability to convert carbohydrates, such as glucose, fructose, xíose, arabinose, rnanosis, galactose, oligosaccharides or polysaccharides into products of
68/83 fermentation. Microorganism fermentation includes strains of the genus Saccharomyces spp. (including, but not limited to, S. cerevisiae (baker's yeast), 8. dystatic, S. uvarum), the genus Kíuyveromyces, (including, but not limited to, K. marxianus, K. fragilis), the genus Candida (including, but not limited to, C. pseudotropicalis and C. brassicae), Pichia stipitis (a relative of Candida shehatae), the genus Çlavispora (including, but not limited to, C. lusitaniae and C. opuntíae), 0 genus Pachysolen (including, but not limited to, P. tannophilus), the genus Bretannomyces (including, but not limited to, for example, 8. cíausenii (Phílippidis, GP, 1996, Cellulose bioconversion technology, in Handbook on Bioethanol: Production and Utilization, Wyman, CE, ed., Taylor & Francis, Washington, DC, 179-212) Other suitable microorganisms include, for example, Zymomonas mobilis, Clostridium spp. (Including, but not limited to, C. thermocellum (Philippidis , 1996, supra), C. saccharobutylacetonicum, C. tyrobutyricum C. saccharobutylicum, C. Punic eum, C. beijernckii, and C. acetobutylicum), Moniliella spp. (including but not limited to pollinis Μ. M. tomentosa, M. madida, M. nlgrescens, M. oedocephali, M, megachilíensis), Yarrowia lipolytica, Aureobasidium SP., Trichosporonoides SP., Trigonopsis variables, Trichosporon SP., Moniliellaacetoabutans SP ., Typhula variabilis, Candida magnoliae, üstílaginomycetes SP., Pseudozyma tsukubaensis, yeast species of the genera Zygosaccharolnyces, Debaryomyces, Hansenula and Pichia and fungi of the dematioid genus Torula (for example, T. corallina).
[62] Many of these microbial strains are publicly available, both commercially and through depositaries, such as the ATCC (American Type Culture Collection, Manassas, Virginia, USA), 0 NRRL (Agricultural Research Sevice Culture Collection, Peoria, Illinois, USA) or The DSMZ (Deutsche Sammlung von Mikroorganismen und Zellkulturen GmbH, Braunschweig, Germany), to name a few.
[63] Commercially available yeasts include, for example,
69/83
Red StarWLesaffre Ethanol Red (available from RedStar / Lesaffre, USA), FALI® (available from Fleischmann's Yeast, a division of Burns Philip Food Ina., USA), SUPERSTAR! ^ (Lallemand Biofuels and Distilled Spirits, Canada) , EAGLE C6 FUEL ™ or C6 FUEL ™ (available from Lallemand Biofuels and Distilled Spirits, Canada) GERT STRAND® (available from Gert Strand AB, Sweden) and FERMOL® (available from DSM Specialties)
DISTILLATION [64] After fermentation, the resulting liquid can be distilled using, for example, a beer column to separate ethanol and other alcohols from most water and solid waste. The steam coming out of the beer column can be, for example 35 % by weight of ethanol and can be fed to a rectification column. A mixture of almost azeotropic ethanol (92.5%) and water from the rectification column can be purified to pure ethanol (99.5%) using molecular vapor phase sieves. The lower parts of the beer column can be sent for the first effect of a three-effect evaporator. The reflux condenser in the rectification column can provide heat for this first effect. After the first effect, the solids can be separated using a centrifuge and dried in a rotary dryer. A portion (25%) of the centrifuge's effluent can be recycled for fermentation and the rest, sent to the second and third effects of the evaporator. Most of the condensate from the evaporator can be returned to the process as reasonably clean condensate, with a small separate portion for wastewater treatment to prevent the accumulation of low boiling compounds.
MATERIALS CONTAINING HYDROCARBONS AND WOOD [65] In other modalities that use the methods and systems described here, materials containing hydrocarbons can be processed.
70/83
The entire process described here can be used in the treatment of all hydrocarbon-containing materials described here. Hydrocarbon-containing materials, as used herein, must include oil sands, oil shale, asphalt sands, coal dust, suspended coal, bitumen, various types of coal and other natural and synthetic materials that include hydrocarbon components and solid matter. Solid matter can include wood, rock, sand, clay, stone, slime, drilling mud, or other organic or inorganic solid materials. The term can also include waste products such as drilling waste and by-products, refinery waste and by-products, or other waste and by-products containing hydrocarbon components, such as gravel and asphalt slabs, asphalt pavers, etc.
[66] In other modalities that use the methods and systems described here, wood and wood-containing materials can be processed. For example, sawn wood products can be processed, such as planks, sheets, laminates, beams, particle boards, composites, rough cut wood, soft wood and hard wood. In addition, cut trees, shrubs, wood chips, sawdust, roots, trunk, stumps, decomposed wood and other wood containing biomass materials can be processed.
TRANSPORT SYSTEMS [67] Various transport systems, including the transport systems discussed here and more, can be used to transport biomass material, for example, as discussed, to a vault, and under an electron beam in a vault. . Exemplary conveyors are belt conveyors, pneumatic conveyors, screw conveyors, cars, trains, trains or trolleys on rails, elevators, front loaders, backhoe loaders, cranes, various scrapers and shovels, trucks, and play devices can be used. Per
71/83 example, vibrating conveyors can be used in various processes described in this document, for example, as disclosed in Provisional Order US 61 / 711,801 filed on October 10, 2012, the entire disclosure of which is incorporated herein by reference.
OTHER MODALITIES [68] Any materials, processes or processed materials discussed here can be used in the production of products and / or intermediates such as compounds, fillers, binders, plastic additives, adsorbents and controlled release agents. Methods can include densification, for example, applying pressure and heat to materials. For example, compounds can be made by combining fibrous materials with a resin or polymer. For example, a radiation resin susceptible to crosslinking, for example, a thermoplastic resin can be combined with fibrous material to provide a fibrous material / resin susceptible to crosslinking. Such materials can be, for example, useful as building materials, protective sheets, containers and other structural materials (for example, molded and / or extruded products). Absorbents can be, for example, in the form of pellets, chips, fibers and / or sheets. Adsorbents can be used, for example, as pet liners, packaging materials or pollution control systems. Controlled release matrices can also be in the form of, for example, pellets, chips, fibers or sheets. Controlled release matrices can, for example, be used to release drugs, biocides, fragrances. For example, composite materials, absorbents and release agents and their uses are described in Serial US No. PCT / US2006 / 010648, filed March 23, 2006 and patent no. 8,074,910 filed on November 22, 2011, the full disclosures which are incorporated herein by reference.
72/83 [69] In some cases, the biomass material is treated on a first level to reduce recalcitrance, for example, using accelerated electrons, to selectively release one or more sugars (for example, xylose). The biomass can then be treated at a second level to release one or more other sugars (for example, glucose). Optionally, the biomass can be dried between treatments. Treatments may include applying chemical and biochemical treatments to release sugars. For example, a biomass material can be treated at a level of less than approximately 20 Mrad (for example, less than approximately 15 Mrad, less than approximately 10 Mrad, less than approximately 5 Mrad, less than approximately 2 Mrad) and then treated with a sulfuric acid solution, containing less than 10% sulfuric acid (for example, less than approximately 9%, less than approximately 8%, less than approximately 7%, less than approximately 6 %, less than about 5%, less than about 4%, less than about 3%, less than about 2% less than about 1%, less than about 0.75%, less than about 0.50% , less than approximately 0.25%) to release xylose. Xylose, for example, which is released in solution, can be separated from the solids and, optionally, the solids can be washed with some solvent / solution (for example, with water and / or acidified water). Optionally, solids can be dried, for example, in air and / or under vacuum optionally with heating (for example, below approximately 150 degrees C, below approximately 120 degrees C) at a water content below approximately 25 wt% (below approximately 20% by weight, below approximately 15% by weight, below approximately 10% by weight, below approximately 5% by weight). The solids can then be treated to a level of less than approximately 30 Mrad (for example, less
73/83 than about 25 Mrad, less than about 20 Mrad, less than about 15 Mrad, less than about 10 Mrad, less than about 5 Mrad, less than about 1 Mrad or even none) and then be treated with an enzyme (for example, a cellulase) to release glucose. Glucose (for example, glucose in solution) can be separated from the remaining solids. The solids can then be further processed, for example, used to make energy or other products (for example, products derived from lignin).
FLAVORS, FRAGRANCES AND DYES [70] Any of the products and / or the intermediates described here, for example, produced by the processes, systems and / or equipment described here, can be combined with flavors, fragrances, dyes and / or mixtures of these . For example, any one or more (optionally together with flavors, fragrances and / or dyes) of sugars, organic acids, fuels, polyols, such as sugar alcohols, biomass, fibers and compounds, can be combined with (for example, formulated , mixed or reacted) or used in the manufacture of other products. For example, one or more of such products can be used in the manufacture of soaps, detergents, sweets, drinks (for example, cola, wine, beer, alcoholic drinks such as gin or vodka, sports drinks, coffees, teas) , drugs, adhesives, sheets (for example, fabrics, nonwovens, filters, wipes) and / or compounds (for example, plates). For example, one or more of such products can be combined with herbs, flowers, petals, spices, vitamins, aromatic sachets or candles. For example, formulated, mixed or reacted combinations may have grapefruit, orange, apple, raspberry, banana, lettuce, celery, cinnamon, chocolate, vanilla, mint, mint, onion, garlic, pepper, saffron, ginger, milk, wine, beer, tea, lean meats, fish, maricos, olive oil, coconut fat, pork fat, butter fat,
74/83 meat broth, vegetables, potatoes, marmalade, ham, coffee and cheese.
[71] Flavors, fragrances and dyes can be added in any amount, such as between about 0.001% by weight to about 30% by weight, for example, between about 0.01 to about 20, between about 0.05 to about from 10 by weight, or between about 0.1% by weight to about 5% by weight. These can be formulated, mixed and or reacted (for example, with any product or intermediate described herein, or more) by any means and in any order or sequence (for example, stirred, mixed, emulsified, gelled, infused, heated, sonicated, and / or suspended). Fillers, binders, emulsifiers, antioxidants can also be used, for example, protein gels, gums and silicone.
[72] In one embodiment, flavors, fragrances and dyes can be added to the biomass immediately after the biomass has been irradiated, so that the reactive points created by the irradiation can react with compatible reactive points of the flavors, fragrances and dyes.
[73] Flavors, fragrances and dyes can be natural and / or synthetic materials. These materials can be one or more of a compound, composition or mixtures thereof (for example, a natural or formulated composition of several compounds). Optionally, flavors, fragrances, antioxidants and dyes can be derived biologically, for example, from a fermentation process (for example, fermentation of saccharified materials as described here). Alternatively, or in addition, these flavors, fragrances and dyes can be harvested from an entire organism (for example, plant, fungus, animal, bacteria or yeast) or from a part of an organism. The organism can be collected and or extracted to provide color, flavors, fragrances and / or antioxidants by any means including the use of
75/83 methods, systems and equipment described here, hot water extraction, supercritical fluid extraction, chemical extraction (eg solvent or reactive extraction including acids and bases), mechanical extraction (eg pressure, comminution, filtration) , using an enzyme, using a bacterium in order to decompose a raw material, and combinations of these methods. The compounds can be derived by a chemical reaction, for example, the combination of a sugar (for example, as produced and described here) with an amino acid (Maillard reaction). The taste, the fragrance. the antioxidant and / or the dye can be an intermediate and or product produced by the methods, equipment or systems described herein, for example an ester and a product derived from lignin.
[74] Some examples of flavor, fragrances and dyes are polyphenols. Polyphenols are pigments responsible for the red, purple and blue coloring of many fruits, vegetables, cereal grains and flowers. Polyphenols can also have anti-oxidant properties and often taste bitter. The anti-oxidant properties make these preservatives important. In the class of polyphenols are flavonoids, such as anthocyanins, flavanonols, flavan-3-ools, s, flavanones and flavanonols. Other phenolic compounds that can be used include phenolic acids and their esters, such as chlorogenic acid and polymeric tannins.
[75] Among inorganic coloring compounds, organic and mineral compounds can be used, for example, titanium dioxide, zinc oxide, aluminum oxide, cadmium yellow (for example, CdS), cadmium orange (for example, CdS with some Se), alizarine red (for example, synthetic or non-synthetic rose madder), ultramarine blue (for example, synthetic ultramarine blue, natural ultramarine blue, synthetic violetultramarine), cobalt blue, cobalt yellow, cobalt green, viridian (for example, hydrated chromium (III) oxide), chalcophilite, conicalcite, cornubite, comwaílite and liroconite. Black pigments such as
76/83 carbon black and self-dispersing black can be used, [76] Some flavors and fragrances that can be used include azalea tbhq, acet 06, allyl amyl gluconate, alpha terpineol, ambrettolide, ambrinol 95, andrane, aphermate, applelide , bacdanol®, bergamal, beta-ionone epoxide, beta naphthyl isobutyl ether, bicyclonalonalactone, bornafix®, cantoxal, cashmeran®, cashmeran® velvet, cassiffix®, cedrafix, cedramber®, cedril acetate, celestolide, dimethyl acetate citral, citrolate ™, citronellol 700, citronellol 950, citronellol coeur, citronelil acetate, pure citronelil portrait, citronelil formate, clarycet, clonal, coniferan, pure coniferan, 50% peomosa aldehyde, cyclabute, cyclacet®, cyclaprop ®, cyclemax ™, cyclohexyl ethyl acetate, apricot !, delta damascene, dihydrate cyclacet, dihydric mircenol, dihydre terpineol, dihydryl terpinyl acetate, dimethyl cyclormol, dimethyl octanol pq, dimircetol, diola, dipentene, dulciny l® recrystallized, ethyl glyldate »3 * phenyl, fleuramone, fleuranil, super floral, floralozone, floriffol, fraistone, fructona, galaxolide® 50, galaxolide® 50 bb, galaxolide® 50 ipm, undiluted galaxolide®, galbascone, generaldehyde, geraniol 5020, geraniol type 600, geraniol 950, geraniol 980 (pure), geraniol coeur eft, geraniol coeur, geranyl coeur acetate, geranil acetate, pure, geranyl formed, gray, guaila acetate, helional ™. herbac, herbalime ™, hexadecanoid, hexalon, hexenll cis-3 salicylate, hyacinth body, no. hyacinth body no., 3, hydrotropic aldehyde dma. hydroxyl, indolarome, intreleven aldehyde, special intreleven acid, alpha ionone, beta ionone, citral isocycle, geraniol isocycle, iso and super®, isobutyl quinoline, jasmal ,, jessemal®, kharismal®, kharismal® super, khusinil, koavone®, kohinool ®, liffarome ™, limoxal, lindenol ™, lyral®, super lyrame, mandarin aldehyde 10% tri eth, citr, maritime, mck chines, meijiff ™, me! Afleur, melozone, methyl anthranilate, extra iononealfa methyl, methyl ionone gamma a , methionone gamma coeur, methionone gamma pure.methyl lavender ketone, montaverdi®, muguesia, muguet aldehyde 50, musk z4, myrac aldehyde, mircenyl acetate, nectarate ™, nerol 900, nerylacetate,
77/83 ocimene, octacetal, orange flower ether, orivone, orríniff 25%, oxaspírane, ozofleur, pamplefíeur®, peomosa, phenoxanol®, piconia, precyclemone b, prenyl acetate.prísmantol, resedâ body, rosemary, musk rose , sanjinoi, santaliff ™, syvertal, terpineol, terpinolene 20, terpinolene 90 pq, terpinolene red, terpinil acetate, jAX terpinilacetato, tetrahydropyran, muguol®, tetrahydro myrcenol, tetrameran, tímbersilk ™, tobacarol _(trimofix® tt, triplal®, trísamber®, vanorís.verdox ™, verdox ™ hc, vertenex®, vertenex® hc.vertofix® coeur, vertoliff, vertoliff iso, víolíff.vivaldie, zenolide, abs india 75 pct miglyol, abs morocco 50 pct dpg, abs morocco 50 pct tec, french absolute, india absolute, md 50pct bb, morocco absolute, pg concentrate, dye 20 pct, ambergris, ambergris absolute, amberete seed oil, mugwort oil 70 pet tuiona, grand vert absolute, abs de basil grand vert md, basil oil grand vert dog, vervein basil oil, vietnamese basil oil, deterpened bay oil, ng beeswax abs, beeswax absolute, siam benzoin resinoid, siam benzoin resinoid 50 pet dpg, sion benzoin resin 50pct pg, sion benzoin resinoid 70.5 pet tec, abs black currant bud 65 pet pg, abs black currant bud md 37 pet tec, abs black migranol bud abs, burgundy black currant bud absolute, bois de rose oil, white absolute, white resinoid, italian broom absolute, guatemalan cardamom co2extract, guatemalan cardamom oil, indian cardamom oil, carrot heart, egyptian acacia absolute, acacia absolute md 50 pet ipm, abs from castoreum 90 pet tec, abs castoreum c 50 pet miglyol, absolute from castoreum, resin from castoreum, resin from castoreum 50 pet dpg, cedrol, cedrene, atlantic cedar oil redist, roman chamomile oil, wild chamomile oil in, wild chamomile oil with low limonene, ceylon cinnamon bark oil, absolute cyste, absolute colorless cyst, citronella oil. iron-free asian, abs civet 75 pet pg, civet absolute, civet tincture 10 pct, deed clear french salvia abs,
78/83 absolute of French clear salvia, colorless clear salvia 50 pct pg, French clear salvia oil, copaiba balm, copaiba balm oil, coriander seed oil, cypress oil, organic cypress oil, davana oil , galbanol, colorless galbanum absolute, galbanum oil, galbanum resinoid, galbanum resinoid 50 pct dpg, hercolinbht galbanum resinoid, tec bht galbanum resinoid, gentian absolute md 20 pct bb, concrete gentian, abs of egyptian geranium md , egyptian geranium absolute, chinese geranium oil, egyptian geranium oil, ginger oil 624, soluble rectified ginger oil, guava wood heart, hay absolute md 50 pct bb, hay absolute, hay absolute md 50 pcttec, paio santo, organic hyssop oil, abs immortelle yugo md 50 pct tec, immortelle absolute spain, immortelle yugo absolute, abs indian jasmine md, egyptian jasmine absolute, ja absolute indian smim, moroccan jasmine absolute, arnbac jasmine absolute, abs jd md 20 pct bb, french jonquil absolute, fig juniper berry oil, soluble rectified juniper berry oil, 50pct tec labinoid resinoid, bb labinoid resinoid , labdanum resinoid md, labdanum resinoid md 50 pct bb, lavine absolute h, lavina absolute md, organic abrina lavine oil, organic coarse lavender oil, lavender oil, super lavender oil, lavender absolute h, lavender absolute md, lavender oil without coumarin, lavender oil without coumarin organic, lavender oil organic maillette, lavender mt oil, mace bb absolute, eugenol low methyl magnolia flower oil, oil and magnolia flower , magnolia flower oil md, magnolia leaf oil, mandarin oil md, mandarin oil md bht, absolute mate mate, tree moss absolute md tex ifra 43, abs moss oak md tec ifra43, absolut oak moss ifra 43, tree moss absolute md ipm ifra 43, myrrh resinoide bb, myrrh resinoid md, myrrh resinoide tec, iron-free blueberry oil, rectified tunisian blueberry oil, abs narcisse md 20pct bb , absolute of narcissus
79/83 french, tunisian neroli oil, deterpened nutmeg oil, oeillet absolute, frankincense resin, bb frankincense resin, frankincense dpg resin, frankincense extra 50 pct dpg, frankincense md resin, frankincense resin md 50 pctdpg, tec olibano resinoid, opoponax tec resinoid, md bht sour orange oil, md scfc sour orange oil, tunisian orange flower absolute, tunisian orange fior water absolute, orange leaf absolute, absolute tunisian orange flower water, italian orris absolute, concrete orris 15pct irona, concrete orris 8 pct irona, natural orris 15 pct irona 4095c, natural orris 8 pctirona 2942c, orris resinoid, osmanto absolute, osmanto absolute md 50 pct bb, patchouli n'3 heart, indonesian patchouli oil, ironless indonesian patchouli oil, md indonesian patchouli oil, redist patchouli oil, pennyroyal heart, absolute of hor telã md, tunisian petitgrain sour orange oil, citronier petitgrain oil, deterpened Paraguayan petitgrain oil, deterpened petitgrain oil, chili berry oil, chili leaf oil, Chinese Rhodinolex geranium, Bulgarian pink low methyl eugenol , low methyl eugenol abs of Moroccan rose, low methyl eugenol of Turkish rose, rose absolute, Bulgarian rose absolute, damask rose absolute, md rose absolute, Moroccan rose absolute, Turkish rose absolute, rose oil, rose oil bulgarian, eugenol low methyl damask rose oil, turkish rose oil, organic camphor rosemary oil, tunisian rosemary oil. indian sandalwood oil, rectified indian sandalwood oil, santalol, schinus molle oil, san lipo tincture john 10 pct, styrax resinoid, tagete oil, tea tree heart, tonka bean abs 50 pct solvents, tonka bean absolute, indian nard absolute, veti heart see extra, Haitian vetiver oil, Haitian vetiver oil md, Javanese vetiver oil, Javanese vetiver oil md, Egyptian violet leaf absolute, Egyptian violet leaf absolute, French violet leaf absolute, leaf absolute violet md 50 pct bb, õíeo de
80/83 alosnadesterpenizado, extra ylang oil, HI ylang oil and combinations of these.
[77] Dyes can be found among those listed in the International Color Index by the Society of Dye and Colorists. Dyes can include dyes and pigments and include those commonly used in the coloring of textile materials, paints, inks and inks for inkjet printing. Some of the dyes that can be used to be used include carotenoids, ariiid yellow, diarylid yellow, β-naphthols, naphthols, benzimidalozones, diazo-type condensation pigments, pyrazolones, nickel-azo yellow, phthalocyanines, quinacridones, perylenes and perinones, indoline and isoindolinone pigments, triarylcarbonium pigments, diceto-pyrrole-pyrol pigments, thioindigoids, Carotenoids include, for example, alpha-carotene, betaoarotene, gamma-carotene, lycopene, lutein and astaxanthin, Annatto extract, beet extract powder, canthaxanthin, caramel, P-Apo-8'-carotenal, mealybug extract, carmine, sodium-copper-chlorophyllin, toasted cotton seed meal and partially degreasing, ferrous gluconate, earthy lactate, grape-colored extract, grape skin extract (enocyanin), carrot oil, paprika, paprika oleoresin, mica-based pearlescent pigments, riboflavins, saffron, titanium dioxide NiO lycopene tomato extract, tomato lycopene concentrate, turmeric, turmeric oleoresin, FD & C Blue No.1, FD & C Blue no. 2, FD&C Verde no. 3, Orange B, Citrus Red no, 2, FD&C Red no, 3, FD&C Red no. 40, FD&C Yellow no. 5, FD&C Yellow no. 6, alumina (dry aluminum hydroxide), calcium carbonate, potassium-sodium-copper-chlorophyllin (copper-chlorophylline complex), Dihydroxyacetone, bismuth oxychloride, terrestrial ammonium ferrocyanide, ferric ferrocyanide, chromium hydroxide green, green chromium oxide, guanine, pyrophyllite. talc, aluminum powder, bronze powder, copper powder, zinc oxide, D&C Blue no. 4, D&C Verde no. 5, D&C Verde no. 6, D&C Verde no. 8, D&C Orange no. 4, D&C Orange no. 5, D&C Orange no.
81/83
10, D&C Orange no. 11, FD&C Red no. 4, D&C Red no. 6, D&C Red No. 7, D&C Red No. 17, D&C. Red No. 21, D&C Red 22. D&C Red No. 27, D&C Red No. 28, D&C Red No. 30, D&C Red No. 31, D&C Red No. 33, D&C Red No.
34, D&C Red No. 36, D&C Red No. 39, D&C Violet No. 2, D&C Yellow No. 7, Ext. D&C Yellow No. 7 Ext, D&C Yellow No. 8, D&C Yellow No. 10, D&C Yellow No 11, D&C Black No. 2, D&C Black No. 3 (3), D&C Brown No. 1, D&C Ext., Chromium-cobalt-aluminum oxide, ferric ammonium citrate, pyrogallol, Campeche extract, copollmers of 1 , 4BlsKS-hydroxy'etilljamino] -9,10-anthracenedione bis (2-propenoic) ester, 1,4Bls [(2 ~ methylphenyl) amino] -9,10-anthracenedione, anthraquinone copollmer 1,4-613 (4- ( 2-methacryloxyethyl) phenylamino], carbazole violet, chlorophyllin-copper complex, chromium-cobalt-aluminum oxide, CJ. Vat Orange 1, 2 [[2,5-Dietoxi- 44 (4-meWfenii) uncle! J fenlljazo] - 1,3,5-benzenetriol, 16,23Dihydrodinafto [2,3-8: 2 ^ 3-1] naphtho [2 ', 3': 6,7] indole [2,3-c] carbazole5,10,15, 17,22,24-hexone, N, N- (9,10-Dihydro- 9,10-dioxo-1,5-anthracenedyl) bisbenzamide, 7,16-Dichloro-6,15-dihydro- 5,9,14 , 18-anthraxinetetrone, 16,17Dimethoxydinafto (1,2,3-cd: 3,2 1 -1m) perylene-5,10-dione, copolymers of hydroxyethyl pollet methacrylate) (3), Reactive Black 5, Reactive Blue 21, Reactive Orange 78, Reactive Yellow 15, Reactive Blue No. 19, Reactive Blue No. 4, CJ. Reactive Red 11, C.l. Reactive Yellow 86, C.l. Reactive Blue 163, CL Reactive Red 180, 4 - ((2,4-dimethylphenyl) azo] - 2,4-dihydro-5-methyl2-phenyl-3H-pyrazol-3-one (Solvent Yellow 18). -2 ~ (6-ethoxy-3oxobenzo [b] thio-2 (3H) - ylidene) benzo [b] thiophene- 3 (2H) -one, Phthalocyanine green, phthalocyanine green, reactive products based on vinyl alcohol paint / methyl methacrylate, Cl Reactive Red 180, CJ. Reactive Black 5, CL Reactive Orange 78, CJ. Reactive Yellow 15, CJ. Reactive Blue 21, Dysodium 1-amino-4 ~ [(4 - (((2-bromo-1 -oxoalyl) amino] -2sulfonatophenyl] amino] -9,10-dihydro-9,10-dioxoanthracene-2-sulfonate (Reactive Blue 69), D&C Blue No. 9. copper [fta! ocyananate (2-)] and mixtures of these.
82/83 [78] In addition to the examples in this document, or unless expressly specified otherwise, all numerical ranges, quantities, values and percentages, such as material quantities, elemental content, reaction times and temperatures, quantities and others, in the following part of the specification and appended claims may be read as if preceded by the word approximately ”, although the term approximately” may appear not expressly with the value, quantity or variety. In this sense, unless otherwise indicated, the numerical parameters established in the following specification and in the appended claims are approximations that may vary depending on the desired properties to be obtained by the present invention. At least, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, at least each numerical parameter must be interpreted taking into account the number of significant digits reported and applying rounding techniques common.
[79] Notwithstanding that the numerical ranges and parameters establishing the broad scope of the invention are approximations, the numerical values established in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contains errors resulting necessarily from the standard deviation found in their respective test measurements. In addition, when numeric ranges are established in this document, these ranges include the various endpoints mentioned (for example, endpoints can be used). When percentages by weight are used in this document, the numerical values reported are relative to the total weight. [80] Also, it should be understood that any numerical range cited in this document is intended to include all sub-ranges subsumed therein, For example, a scale from 1 to 10 is intended to include
83/83 all sub intervals between (and starting) the minimum value of 1 and the maximum value of 10, that is, having a minimum value equal to or greater than 1 and a maximum value equal to or less than 10. The terms ”one ₍ '' a ', or one' in this document is intended to include at least one ”or one or more” unless otherwise indicated.
[81] Any patent, publication or other disclosure material, in whole or in part, that is, said to be incorporated by reference in this document, is incorporated here only insofar as the incorporated material does not conflict with the definitions, statements or other existing disclosure material set out in this disclosure. As such and to the extent necessary, the disclosure so explicitly set forth in this document supersedes any conflicting material incorporated herein by reference. Any material, or part of it, that is said to be incorporated by reference in this document, but which conflicts with the definitions, statements, or other disclosure material contained herein will only be incorporated to the extent that there is no conflict between the material and the existing disclosure material.
[82] While this invention has been particularly shown and described with reference to its preferred modalities, it will also be understood by those skilled in the art that various changes in shape and details can be made, without departing from the scope of the invention encompassed by attached claims.

权利要求:
Claims (27)
[1]
1. Method for protecting material processing equipment, the method characterized by the fact that it comprises;
transporting a biomass material under an electron beam in a conveyor, and compartmentalizing engine components in a radiation-opaque equipment compartment.
[2]
2. Method according to claim 1, characterized by the fact that the equipment compartment opaque to radiation is purged with gas.
[3]
3. Method, according to claim 1 or 2, characterized by the fact that changing the gas in the equipment compartment at an exchange rate less than once every 10 minutes.
[4]
4. Method according to any one of the above claims, characterized by the fact that the gas is selected from the group consisting of air, oxygen reduced to air, nitrogen, argon, helium, carbon dioxide and mixtures thereof.
[5]
5. Method, according to any of the above claims, characterized by the fact that the carrier is arranged inside a safe.
[6]
6. Method according to claim 5, characterized by the fact that the safe also contains irradiation equipment.
[7]
7. Method according to claim 1, characterized by the fact that gas is supplied from inside the safe and the method additionally comprises filtering the gas before purging the equipment compartment with gas.
[8]
8. Method according to claim 7, characterized by the fact
2/4 that the gas has been filtered to remove ozone.
[9]
9. Method according to any of the above claims, characterized by the fact that the method additionally includes moving the equipment compartment to access the engine components.
[10]
10. Method according to claim 9, characterized by the fact that the equipment compartment is configured to be mobile.
[11]
11. Method according to any of the above claims, characterized by the fact that the equipment compartment includes lead.
[12]
12. Method according to any of the above claims, characterized by the fact that the exposure of the engine components to radiation is reduced by at least 10% compared to the radiation exposure that would occur without the equipment compartment.
[13]
13. Method according to any one of the above claims, characterized by the fact that the conveyor is a vibrating conveyor.
[14]
14. Method according to any one of the above claims, characterized in that it additionally comprises providing a gap between the equipment compartment and the vibrating conveyor to accommodate the movement of components of the vibrating conveyor during use.
[15]
15. System to protect an engine and other engine components from a vibrating conveyor, the system characterized by the fact that it comprises:
a vibrating conveyor having motor components mounted on a frame; and a radiation-opaque equipment compartment
3/4 substantially configured to be positioned on the engine and having an open end that is dimensioned to provide an intervening between the equipment compartment and the frame when the equipment compartment is in place.
[16]
16. System according to claim 1, characterized by the fact that the gap is maintained by the equipment compartment in relation to the conveyor using a limiter, a groove, a spacer and / or a fastener.
[17]
17. System according to claim 15, characterized by the fact that it additionally includes a conduits configured to flow a purge gas in the equipment compartment.
[18]
18. System according to any one of the above claims, characterized by the fact that it additionally includes equipment for moving equipment compartment in and out of position on the conveyor components.
[19]
19. System according to claim 17, characterized by the fact that the equipment is selected from wheels attached to the equipment compartment, tracks for sliding the equipment compartment, wheels arranged below the equipment compartment (for example, attached to the equipment compartment). floor), slides (for example, slide rails), linear guides and their combinations.
[20]
20. Method according to any of the above claims, characterized by the fact that the exposure of the engine components to radiation is reduced by at least 20% compared to the radiation exposure that would occur without the equipment compartment.
[21]
21. Method according to any of the above claims, characterized by the fact that the exposure of the engine components to radiation is reduced by at least 30% compared to the exposure
4/4 to radiation that would occur without the equipment compartment.
[22]
22. Method according to any of the above claims, characterized by the fact that the exposure of the engine components to radiation is reduced by at least 50% compared to the radiation exposure that would occur without the equipment compartment.
[23]
23. Method according to any of the above claims, characterized by the fact that the exposure of the engine components to radiation is reduced by at least 70% compared to the radiation exposure that would occur without the equipment compartment.
[24]
24. Method according to any of the above claims, characterized by the fact that the exposure of the engine components to radiation is reduced by at least 90% compared to the radiation exposure that would occur without the equipment compartment.
[25]
25. Method according to claim 2, characterized by the fact that the gas comprises air.
[26]
26. Method for protecting material processing equipment, the method characterized by the fact that it understands;
transporting biomass material under an electron beam in a conveyor, and compartmentalizing components in a radiation-opaque equipment compartment.
[27]
27. Method according to claim 26, characterized by the fact that the components comprise

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CA2885396A1|2014-04-17|

---

AU2013329217B2|2017-04-13|

---

JP2018069239A|2018-05-10|

---

JP2015534073A|2015-11-26|

---

EP2890797A4|2016-05-25|

---

MX355649B|2018-04-26|

---

NZ706115A|2018-06-29|

---

IL254090D0|2017-10-31|

---

SG11201502088XA|2015-05-28|

---

EP2890489A4|2016-05-25|

---

AU2019201804A1|2019-04-04|

---

KR20150067144A|2015-06-17|

---

CU20150035A7|2016-03-31|

---

US10163535B2|2018-12-25|

引用文献:

---

公开号 | 申请日 | 公开日 | 申请人 | 专利标题

---

---

US1525035A|1921-06-02|1925-02-03|Huth Christian|Packing apparatus|

---

US1924078A|1928-05-12|1933-08-22|Brogdex Co|Apparatus for handling fresh fruits|

---

US1789407A|1928-09-07|1931-01-20|Messrs Boggild & Jacobsen|Duplex vibrating table|

---

US1962573A|1931-08-21|1934-06-12|Firm Gebruder Buhler|Sifting machine for middlings, semolina, and the like, particularly grits|

---

US2144382A|1936-04-09|1939-01-17|Allis Chalmers Mfg Co|Low head vibrating screen|

---

US2467748A|1946-01-08|1949-04-19|Jeffrey Company|Vibratory motor|

---

US2630209A|1946-04-26|1953-03-03|Carrier Conveyor Corp|Helical vibratory conveyer|

---

US2566316A|1946-08-03|1951-09-04|Allis Chalmers Mfg Co|Vibrator|

---

US2674381A|1946-08-27|1954-04-06|Ajax Flexible Coupling Co Inc|Discrete material conveyer and distributor|

---

US2697236A|1950-01-31|1954-12-21|Mccain|Machine for gluing book backs|

---

US2669344A|1950-09-23|1954-02-16|Jeffrey Mfg Co|Balanced sectionalized vibratory conveyer|

---

US2681637A|1950-12-04|1954-06-22|Masonite Corp|Coating apparatus for applying a resin in particulate form|

---

US2680815A|1950-12-28|1954-06-08|High Voltage Engineering Corp|Method of and apparatus for treating substances with high energy electrons|

---

US2686733A|1951-07-17|1954-08-17|Dunlop Tire & Rubber Corp|Production of pile fabrics|

---

GB721235A|1952-06-12|1955-01-05|High Voltage Engineering Corp|Improvements in or relating to method of irradiating matter with electrons|

---

US2843255A|1953-08-31|1958-07-15|Jeffrey Mfg Co|Conveyer apparatus|

---

US2819047A|1953-12-01|1958-01-07|Carrier Conveyor Corp|Conveyor for mixing and de-aerating|

---

US2814379A|1954-02-03|1957-11-26|Sernetz Heinz|Vibratory conveyor having two oppositely vibrating feed members|

---

US2789733A|1954-07-02|1957-04-23|Jr William L Secord|Vibrating feeder|

---

US2798699A|1954-07-07|1957-07-09|St Regis Paper Co|Vibrating conveyor with oscillating side plates|

---

US2853180A|1954-12-22|1958-09-23|Robert C White|Vibrating conveyor|

---

US2993120A|1959-01-14|1961-07-18|High Voltage Engineering Corp|Electron irradiation|

---

US3712459A|1971-02-12|1973-01-23|Gen Kinematics Corp|Vibratory conveyor|

---

JPS5028515B2|1971-09-30|1975-09-16|

---

US3939286A|1973-01-29|1976-02-17|Jelks James W|Process for oxidizing and hydrolyzing plant organic matter particles to increase the digestability thereof by ruminants|

---

US3934144A|1974-04-11|1976-01-20|United States Steel Corporation|X-ray machine for rapid and precise inspection of mixed sizes of pneumatic tires|

---

US4218410A|1975-06-28|1980-08-19|Leybold-Heraeus Gmbh & Co. Kg|Method for the production of high-purity metal powder by means of electron beam heating|

---

DE2528999C2|1975-06-28|1984-08-23|Leybold-Heraeus GmbH, 5000 Köln|Process and device for the production of high-purity metal powder by means of electron beam heating|

---

US4268505A|1978-04-13|1981-05-19|Kureha Kagaku Kogyo Kabushiki Kaisha|Pharmaceutical composition comprising a nitrogen-containing polysaccharide and an antibiotic agent, and a method of treating an infectious disease therewith|

---

AT798T|1978-06-15|1982-04-15|Imperial Chemical Industries Plc|ANTI-INFLAMMATORY 1-PHE NYL-2-AMINOAETHANOL DERIVATIVES, METHOD FOR THE PRODUCTION THEREOF AND THEIR PHARMACEUTICAL COMPOSITIONS FOR LOCAL USE.|

---

US4337152A|1978-09-27|1982-06-29|Frebar Holding Ag|Aeration apparatus and method|

---

US4305000A|1978-11-03|1981-12-08|Tetra Pak Developpement Ltd.|Process of and apparatus for cold-cathode electron-beam generation for sterilization of surfaces and similar applications|

---

US4275163A|1978-11-20|1981-06-23|The United States Of America As Represented By The Secretary Of The Army|Cellulase-producing microorganism|

---

SU956478A1|1978-11-27|1982-09-07|Предприятие П/Я М-5885|Process for producing furfuryl alcohol|

---

US4260051A|1979-02-21|1981-04-07|Burghart George L|Vibratory conveyor system with counter vibration component and non-vibrating support|

---

US4243750A|1979-05-29|1981-01-06|National Distillers And Chemical Corp.|Process for the hydrolysis of starch and the continuous fermentation of the sugars obtained therefrom to provide ethanol|

---

US4274163A|1979-07-16|1981-06-23|The Regents Of The University Of California|Prosthetic fixation technique|

---

DE2950014A1|1979-12-12|1981-06-19|Bayer Ag, 5090 Leverkusen|METHOD AND DEVICE FOR A WASHING PROCESS AFTER SPINDING OF CHEMICAL FIBERS|

---

DK187280A|1980-04-30|1981-10-31|Novo Industri As|RUIT REDUCING AGENT FOR A COMPLETE LAUNDRY|

---

JPS6250943B2|1980-09-26|1987-10-27|Fujitsu Ltd|

---

US4321328A|1980-12-05|1982-03-23|Hoge William H|Process for making ethanol and fuel product|

---

JPS5819424U|1981-07-03|1983-02-05|

---

JPS6140006B2|1981-07-28|1986-09-06|Kawasaki Steel Co|

---

US4482046A|1982-04-15|1984-11-13|General Kinematics Corporation|Flexible trough vibratory conveyor|

---

DE3422005A1|1984-06-14|1985-12-19|Messerschmitt-Bölkow-Blohm GmbH, 8012 Ottobrunn|METHOD AND DEVICE FOR DERIVING A STORAGE SIGNAL FOR AN EARTH SATELLITE IN AN ORBIT BY MEANS OF AN EARTH HORIZON SENSOR|

---

JPS6124700U|1984-07-16|1986-02-14|

---

JPS6178390A|1984-09-25|1986-04-21|Japan Atom Energy Res Inst|Pretreatment for saccharification and fermentation of waste resource of cellulose|

---

US4760264A|1986-01-16|1988-07-26|Barrett Lawrence G|Irradiator and method of using irradiator to irradiate|

---

CH671562A5|1987-03-05|1989-09-15|Sig Schweiz Industrieges|

---

AU603879B2|1987-04-06|1990-11-29|Nippon Steel Corporation|Apparatus and method for feeding sintering raw mix|

---

USRE33935E|1987-04-06|1992-05-26|Apparatus and method for feeding sintering raw mix|

---

CN1009757B|1987-04-06|1990-09-26|新日本制铁株式会社|Apparatus and method for feeding sintering raw mix|

---

US4813532A|1988-01-15|1989-03-21|Allen Fruit Co., Inc.|Natural frequency vibratory conveyor|

---

IT1219942B|1988-05-13|1990-05-24|Fidia Farmaceutici|POLYSACCHARIDIC ESTERS|

---

JPH0346319A|1989-07-14|1991-02-27|Fujitsu Ltd|Exposure by x-rays|

---

US5024145A|1989-08-28|1991-06-18|Flakee Mills, Inc.|Vibratory bulk material processor and method|

---

US5055204A|1989-08-29|1991-10-08|Bogart John D|Soil and sludge treatment apparatus and method including agitation, aeration and recirculation|

---

US5131525A|1989-10-17|1992-07-21|General Kinematics Corporation|Vibratory conveyor|

---

US5181715A|1989-12-15|1993-01-26|Canon Kabushiki Kaisha|Sheet conveying unit and system using the same|

---

JPH0427386A|1990-05-24|1992-01-30|Kao Corp|Protease-resistant cellulase, microorganism producing thereof and production of same cellulase|

---

US5530255A|1990-08-17|1996-06-25|Raychem Corporation|Apparatus and methods for electron beam irradiation|

---

KR950000074B1|1991-03-28|1995-01-09|금호석유화학 주식회사|Copolymer of sulfur dioxide and nuclear-substited trialkyl-germylsyrene|

---

IT1254119B|1991-09-13|1995-09-08|Fidia|ESTERS OF CARBOXYLIC DERIVATIVES OF POLYSACCHARIDES|

---

US5426024A|1992-10-23|1995-06-20|Centro De Investigacion Y De Estudios Avanzados Del Instituto Politecnico Nacional|Fermentation method and fermentor|

---

US5401973A|1992-12-04|1995-03-28|Atomic Energy Of Canada Limited|Industrial material processing electron linear accelerator|

---

DE4326146A1|1993-08-04|1995-02-09|Koeberlein Josef Masch|Vibration linear conveyor|

---

US6268196B1|1993-12-17|2001-07-31|Genencor International, Inc.|Method and compositions for treating cellulose containing fabrics using truncated cellulase enzyme compositions|

---

CA2142230A1|1994-03-21|1995-09-22|Samuel V. Nablo|Data reduction system for real time monitoring of radiation machinery|

---

JP3590963B2|1994-12-22|2004-11-17|株式会社Ｎｈｖコーポレーション|Electron beam irradiation device|

---

US5621270A|1995-03-22|1997-04-15|Litton Systems, Inc.|Electron window for toxic remediation device with a support grid having diverging angle holes|

---

JP3340282B2|1995-06-26|2002-11-05|日立造船株式会社|Electrostatic sorting device|

---

CA2159531A1|1995-09-29|1997-03-30|Courtland B. Lawrence|Method for monitoring absorbed dose in an electron beam|

---

JP3291437B2|1995-10-17|2002-06-10|株式会社荏原製作所|Method and apparatus for cooling window foil of electron beam accelerator|

---

US5753474A|1995-12-26|1998-05-19|Environmental Energy, Inc.|Continuous two stage, dual path anaerobic fermentation of butanol and other organic solvents using two different strains of bacteria|

---

US5816386A|1996-07-15|1998-10-06|Allan M. Carlyle|Fluidizer conveyor|

---

US6220427B1|1996-10-12|2001-04-24|Koenig & Bauer Aktiengesellschaft|Conveyor|

---

US5839954A|1996-10-23|1998-11-24|Byron Enterprises Inc.|Sweet corn processing system|

---

US5847401A|1996-11-01|1998-12-08|Atomic Energy Of Canada Limited|Simultaneous double sided irradiation|

---

US6011008A|1997-01-08|2000-01-04|Yissum Research Developement Company Of The Hebrew University Of Jerusalem|Conjugates of biologically active substances|

---

JPH10263521A|1997-03-27|1998-10-06|Kameda Kazuhisa|Reforming treatment of contaminated soil and its system|

---

US5994706A|1997-05-09|1999-11-30|Titan Corporation|Article irradiation system in which article-transporting conveyor is closely encompassed by shielding material|

---

US5916780A|1997-06-09|1999-06-29|Iogen Corporation|Pretreatment process for conversion of cellulose to fuel ethanol|

---

US5851266A|1997-06-23|1998-12-22|Praxair Technology,Inc.|Hybrid solid electrolyte ionic conductor systems for purifying inert gases|

---

US5916929A|1997-06-23|1999-06-29|E-Beam Services, Inc.|Method for irradiating organic polymers|

---

US7537826B2|1999-06-22|2009-05-26|Xyleco, Inc.|Cellulosic and lignocellulosic materials and compositions and composites made therefrom|

---

JPH11169438A|1997-12-10|1999-06-29|Ishikawajima Harima Heavy Ind Co Ltd|Electron beam irradiation device|

---

JPH11192078A|1997-12-29|1999-07-21|Yasuma Kk|Sterilization of vegetable food by low energy electron beam|

---

US5876505A|1998-01-13|1999-03-02|Thermo Fibergen, Inc.|Method of producing glucose from papermaking sludge using concentrated or dilute acid hydrolysis|

---

US5882737A|1998-03-20|1999-03-16|Eckhoff; Paul S.|Apparatus and method for radiation processing of materials|

---

DE19822993C2|1998-05-22|2002-11-14|Siemens Ag|Plant for processing residual material|

---

JP3648537B2|1998-05-25|2005-05-18|株式会社Ｎｈｖコーポレーション|Electron beam irradiation device|

---

US6127687A|1998-06-23|2000-10-03|Titan Corp|Article irradiation system having intermediate wall of radiation shielding material within loop of conveyor system that transports the articles|

---

US6112883A|1998-08-04|2000-09-05|General Kinematics Corporation|Vibratory distribution conveyor|

---

ID29093A|1998-10-16|2001-07-26|Lanisco Holdings Ltd|DEEP CONVERSION THAT COMBINES DEMETALIZATION AND CONVERSION OF CRUDE OIL, RESIDUES OR HEAVY OILS BECOME LIGHTWEIGHT LIQUID WITH COMPOUNDS OF OXYGENATE PURE OR PURE|

---

US6163981A|1998-11-25|2000-12-26|Nilsson; Bengt|Method and apparatus for drying wood particles|

---

US6191424B1|1998-12-03|2001-02-20|I-Ax Technologies|Irradiation apparatus for production line use|

---

US6545398B1|1998-12-10|2003-04-08|Advanced Electron Beams, Inc.|Electron accelerator having a wide electron beam that extends further out and is wider than the outer periphery of the device|

---

US6528800B1|1999-03-03|2003-03-04|Steris, Inc.|Particulate curing system|

---

JP2000254486A|1999-03-09|2000-09-19|Nissin High Voltage Co Ltd|Device and method for electron beam irradiation and material to be treated|

---

JP2000304900A|1999-04-22|2000-11-02|Natl Food Res Inst|Electron beam irradiation device and particle sterilizing method|

---

US6429444B1|1999-08-24|2002-08-06|Steris Inc.|Real time monitoring of electron beam radiation dose|

---

US6276518B1|1999-08-30|2001-08-21|Key Technology, Inc.|Vibratory drive for a vibratory conveyor|

---

US6241858B1|1999-09-03|2001-06-05|Flex Products, Inc.|Methods and apparatus for producing enhanced interference pigments|

---

US6713773B1|1999-10-07|2004-03-30|Mitec, Inc.|Irradiation system and method|

---

US6486481B1|1999-11-12|2002-11-26|Ausimont Usa, Inc.|Vibratory table apparatus and associated equipment and methods for radiation treatment of polymeric materials|

---

DK1259466T3|2000-02-17|2009-01-05|Univ Denmark Tech Dtu|Process for the preparation of lignocellulosic material|

---

AU4533801A|2000-02-24|2001-09-03|Mitec Inc|Bulk material irradiation system and method|

---

JP2001242297A|2000-02-28|2001-09-07|Nissin High Voltage Co Ltd|Electron beam irradiation method and device|

---

JP2001242298A|2000-02-29|2001-09-07|Mitsubishi Electric Corp|Charged-particle beam irradiation device and x-ray irradiation device|

---

US6707049B1|2000-03-21|2004-03-16|Mitec Incorporated|Irradiation system with compact shield|

---

JP2001318200A|2000-05-08|2001-11-16|Nissin High Voltage Co Ltd|Electron beam irradiator|

---

JP2002028520A|2000-07-17|2002-01-29|Sankyu Inc|Method for breaking plastic refuse bag|

---

US6588363B1|2000-08-17|2003-07-08|Paul J. Svejkovsky|Seasoning system and method|

---

JP2002085029A|2000-09-07|2002-03-26|Nisshin Seifun Group Inc|Electron beam irradiator|

---

US20090203079A1|2000-10-20|2009-08-13|Board Of Trustees Of Michigan State University|Transgenic monocot plants encoding beta-glucosidase and xylanase|

---

US6460680B1|2000-10-25|2002-10-08|Key Technology, Inc.|Diverter assembly for use with a vibratory conveyor|

---

JP2002141200A|2000-10-31|2002-05-17|Toshiba Corp|Electron beam device|

---

US6628750B1|2000-11-09|2003-09-30|Steris Inc.|System for electron and x-ray irradiation of product|

---

US6617596B1|2000-11-17|2003-09-09|Steris Inc.|On-line measurement of absorbed electron beam dosage in irradiated product|

---

JP2002171949A|2000-12-07|2002-06-18|Ishikawajima Harima Heavy Ind Co Ltd|Electron beam sterilization method and electron beam sterilizer|

---

US6780448B1|2001-02-06|2004-08-24|David Howard|Pasteurization of food products|

---

JP2004532403A|2001-03-20|2004-10-21|アドバンスト・エレクトロン・ビームズ・インコーポレーテッド|Electron beam irradiation device|

---

US20020135290A1|2001-03-21|2002-09-26|Advanced Electron Beams, Inc.|Electron beam emitter|

---

JP2002272371A|2001-03-22|2002-09-24|Kawasaki Kiko Co Ltd|Apparatus for removing foreign material|

---

CA2443150A1|2001-04-02|2002-10-10|Mitec Incorporated|Irradiation system and method|

---

US7193129B2|2001-04-18|2007-03-20|Mendel Biotechnology, Inc.|Stress-related polynucleotides and polypeptides in plants|

---

US6575084B2|2001-06-01|2003-06-10|Surebeam Corporation, Inc.|System for, and method of, irradiating food products|

---

US6608882B2|2001-06-13|2003-08-19|Surebeam Corporation|System for, and method of, irradiating articles particularly articles with variable dimensions|

---

JP2003029000A|2001-07-16|2003-01-29|Nissin High Voltage Co Ltd|Method for shortening oxygen concentration reduction time in electron beam irradiation apparatus, and the apparatus|

---

WO2003010339A1|2001-07-24|2003-02-06|Arkenol, Inc.|Separation of xylose and glucose|

---

JP2003111356A|2001-10-01|2003-04-11|Mitsubishi Electric Corp|Air-cooled fully-enclosed rotating electric machine|

---

US6750461B2|2001-10-03|2004-06-15|Si Diamond Technology, Inc.|Large area electron source|

---

US6932286B2|2001-11-07|2005-08-23|Fred P. Smith|Combination drop and broadcast spreader|

---

US7019155B2|2001-11-13|2006-03-28|Invista North America S.A.R.L.|Hydrogenation of tetrahydroxybutane to tetrahydrofuran|

---

US6583423B2|2001-11-16|2003-06-24|Ion Beam Applications, S.A.|Article irradiation system with multiple beam paths|

---

JP2003156598A|2001-11-20|2003-05-30|Mitsubishi Heavy Ind Ltd|Method and system for preventing ozone from flowing out in electron beam irradiator|

---

JP2003153987A|2001-11-22|2003-05-27|Mitsubishi Heavy Ind Ltd|Electron beam irradiation device|

---

US20030203454A1|2002-02-08|2003-10-30|Chotani Gopal K.|Methods for producing end-products from carbon substrates|

---

US6838678B1|2002-04-10|2005-01-04|Seagate Technology Llc|Apparatus for inline continuous and uniform ultraviolet irradiation of recording media|

---

US20040005674A1|2002-04-30|2004-01-08|Athenix Corporation|Methods for enzymatic hydrolysis of lignocellulose|

---

CA2404798C|2002-09-24|2007-02-20|Edward W. Chan|Nozzle/mixer assembly|

---

US6914253B2|2002-10-24|2005-07-05|Steris Inc.|System for measurement of absorbed doses of electron beams in an irradiated object|

---

US6808600B2|2002-11-08|2004-10-26|Kimberly-Clark Worldwide, Inc.|Method for enhancing the softness of paper-based products|

---

US7356115B2|2002-12-04|2008-04-08|Varian Medical Systems Technology, Inc.|Radiation scanning units including a movable platform|

---

JP4272878B2|2002-12-13|2009-06-03|岩崎電気株式会社|Electron beam irradiation device|

---

US7604967B2|2003-03-19|2009-10-20|The Trustees Of Dartmouth College|Lignin-blocking treatment of biomass and uses thereof|

---

WO2004097845A2|2003-05-01|2004-11-11|Stirling Andrew J|Improvements in shielded irradiation zone of production line|

---

JP4103699B2|2003-06-30|2008-06-18|株式会社Ｎｈｖコーポレーション|Electron beam irradiation device|

---

SE0302024D0|2003-07-08|2003-07-08|Tetra Laval Holdings & Finance|Device and method of sterilization|

---

US20050077472A1|2003-10-10|2005-04-14|Steris Inc.|Irradiation system having cybernetic parameter acquisition system|

---

US8146894B2|2004-06-21|2012-04-03|Hills Blair H|Apparatus for mixing gasses and liquids|

---

US7402428B2|2004-09-22|2008-07-22|Arborgen, Llc|Modification of plant lignin content|

---

DK176540B1|2004-09-24|2008-07-21|Cambi Bioethanol Aps|Process for the treatment of biomass and organic waste in order to extract desired biologically based products|

---

CA2592950C|2005-01-03|2013-01-22|Western Oil Sands, Inc.|Nozzle reactor and method of use|

---

WO2006092045A1|2005-03-04|2006-09-08|Fpinnovations|Method for determining chemical pulp kappa number with visible-near infrared spectrometry|

---

ES2397791T3|2005-03-24|2013-03-11|Xyleco, Inc.|Fibrous material manufacturing method|

---

EP1869197A2|2005-04-12|2007-12-26|E.I. Dupont De Nemours And Company|Treatment of biomass to obtain ethanol|

---

NZ562363A|2005-04-19|2011-02-25|Archer Daniels Midland Co|Process for the production of animal feed and ethanol and novel animal feed|

---

JP2007051996A|2005-08-19|2007-03-01|Ngk Insulators Ltd|Electron beam irradiation device|

---

US7608689B2|2005-09-30|2009-10-27|Novozymes, Inc.|Methods for enhancing the degradation or conversion of cellulosic material|

---

FI20051145A0|2005-11-11|2005-11-11|Kemira Oyj|New pulp and process for pulping|

---

US20070134781A1|2005-12-12|2007-06-14|Agblevor Foster A|Method for producing bioethanol from a lignocellulosicbiomass and recycled paper sludge|

---

BRPI0715442B1|2006-07-21|2018-01-30|Xyleco, Inc.|METHOD FOR PRODUCING PRODUCTS FROM BIOMASS CELLULOSTIC OR LIGNOCELLULOSTIC MATERIAL|

---

CA2868671C|2006-10-26|2016-12-20|Xyleco, Inc.|Methods of processing biomass comprising electron-beam radiation|

---

JP4928254B2|2006-12-28|2012-05-09|日本製紙株式会社|Method for saccharification of cellulose-containing materials|

---

US20080210718A1|2007-01-25|2008-09-04|General Kinematics Corporation|Fluid-Cooled Vibratory Apparatus, System and Method for Cooling|

---

US20080248540A1|2007-04-03|2008-10-09|The Ohio State University|Methods of producing butanol|

---

KR100873700B1|2007-06-25|2008-12-12|사단법인 한국가속기 및 플라즈마 연구협회|Method of producing bio-fuel using electron beam|

---

CN101680004A|2007-06-27|2010-03-24|诺维信公司|methods for producing fermentation products|

---

US20090188355A1|2007-10-22|2009-07-30|Lindee Scott A|Stack Completion and Scrap Discharge System for a Food Article Slicing Machine|

---

GB0725308D0|2007-12-28|2008-02-06|Holliday R|Combined heater and conveyor|

---

US8236535B2|2008-04-30|2012-08-07|Xyleco, Inc.|Processing biomass|

---

US7846295B1|2008-04-30|2010-12-07|Xyleco, Inc.|Cellulosic and lignocellulosic structural materials and methods and systems for manufacturing such materials|

---

CA2722560C|2008-04-30|2019-09-17|Xyleco, Inc.|Processing biomass|

---

US20110111456A1|2009-04-03|2011-05-12|Xyleco, Inc.|Processing biomass|

---

US7867359B2|2008-04-30|2011-01-11|Xyleco, Inc.|Functionalizing cellulosic and lignocellulosic materials|

---

US8212087B2|2008-04-30|2012-07-03|Xyleco, Inc.|Processing biomass|

---

US20100124583A1|2008-04-30|2010-05-20|Xyleco, Inc.|Processing biomass|

---

US8911833B2|2008-04-30|2014-12-16|Xyleco, Inc.|Textiles and methods and systems for producing textiles|

---

US7931784B2|2008-04-30|2011-04-26|Xyleco, Inc.|Processing biomass and petroleum containing materials|

---

US7867358B2|2008-04-30|2011-01-11|Xyleco, Inc.|Paper products and methods and systems for manufacturing such products|

---

EP2128226A1|2008-05-19|2009-12-02|Furanix Technologies B.V|Fuel component|

---

EA201401307A1|2008-06-18|2015-07-30|Ксилеко, Инк.|PROCESSING OF MATERIALS UNDER THE EFFECT OF ION BEAMS|

---

US8025098B2|2008-06-18|2011-09-27|Xyleco, Inc.|Processing hydrocarbons|

---

US20120040408A1|2008-06-20|2012-02-16|Decker Stephen R|Processing cellulosic biomass|

---

JP2010008387A|2008-06-30|2010-01-14|Iwasaki Electric Co Ltd|Electron beam irradiation equipment|

---

US7900857B2|2008-07-17|2011-03-08|Xyleco, Inc.|Cooling and processing materials|

---

JP2010041923A|2008-08-08|2010-02-25|Oji Paper Co Ltd|Enzymatic saccharification method and ethanol production method|

---

US20100230270A1|2008-09-30|2010-09-16|Global Resource Corporation|Microwave-based conveying devices and processing of carbonaceous materials|

---

EP2350174B1|2008-10-28|2017-12-20|Xyleco, Inc.|Processing materials|

---

EP2367914A4|2008-11-17|2013-05-01|Xyleco Inc|Processing biomass|

---

CA2739704C|2008-11-20|2015-08-18|E.I. Du Pont De Nemours And Company|Process for producing a sugar solution by combined chemical and enzymatic saccharification of polysaccharide enriched biomass|

---

NZ713552A|2008-12-19|2016-08-26|Xyleco Inc|Processing hydrocarbon containing materials|

---

UA103070C2|2009-01-26|2013-09-10|Ксилеко, Инк.|Method for biomass processing|

---

KR101925460B1|2009-02-11|2018-12-05|질레코 인코포레이티드|Processing biomass|

---

UA116325C2|2009-02-11|2018-03-12|Ксілеко, Інк.|Saccharifying biomass|

---

US20100229256A1|2009-03-05|2010-09-09|Metabolix, Inc.|Propagation of transgenic plants|

---

KR101822780B1|2009-05-20|2018-01-26|질레코 인코포레이티드|Bioprocessing|

---

MX344902B|2009-05-20|2017-01-11|Xyleco Inc|Processing hydrocarbon-containing materials.|

---

EP2432888A1|2009-05-20|2012-03-28|Xyleco, Inc.|Processing biomass|

---

US8636402B2|2009-05-20|2014-01-28|Xyleco, Inc.|Processing biomass|

---

JP2011024545A|2009-07-29|2011-02-10|Nippon Paper Industries Co Ltd|Method for producing saccharide from cellulose-containing material|

---

WO2011063500A1|2009-11-24|2011-06-03|National Research Council Of Canada|Process for preparing furfural from xylose|

---

JP2011182646A|2010-03-04|2011-09-22|Hamamatsu Photonics Kk|Method for treating lignocellulose-based biomass|

---

US9242222B2|2010-04-19|2016-01-26|The University Of Toledo|Aldose-ketose transformation for separation and/or chemical conversion of C6 and C5 sugars from biomass materials|

---

US8697404B2|2010-06-18|2014-04-15|Butamax Advanced Biofuels Llc|Enzymatic production of alcohol esters for recovery of diols produced by fermentation|

---

US8710279B2|2010-07-09|2014-04-29|Celanese International Corporation|Hydrogenolysis of ethyl acetate in alcohol separation processes|

---

US8852901B2|2010-07-19|2014-10-07|Xyleco, Inc.|Processing biomass|

---

NZ609261A|2010-10-20|2015-04-24|Xyleco Inc|Method for treating lignocellulosic material by irradiating with an electron beam|

---

CN201820467U|2010-10-21|2011-05-04|浙江银都辐照技术有限公司|Irradiation system for conveniently and quickly removing ozone|

---

JP5621567B2|2010-12-10|2014-11-12|澁谷工業株式会社|Electron beam sterilizer|

---

MY170871A|2011-06-09|2019-09-11|Xyleco Inc|Processing biomass|

---

JP6088972B2|2011-09-27|2017-03-01|株式会社カネカ| acryloyl-terminated polyisobutylene polymer, method for producing the same, and active energy ray-curable composition|

---

US9029614B2|2011-12-14|2015-05-12|Celanese International Corporation|Phasing reactor product from hydrogenating acetic acid into ethyl acetate feed to produce ethanol|

---

JP2012076929A|2011-12-15|2012-04-19|Shibuya Seiki Co Ltd|Roller conveyor|

---

MY169799A|2011-12-22|2019-05-16|Xyleco Inc|Processing biomass for use in fuel cells related applications|

---

CA2858302A1|2011-12-22|2013-06-27|Xyleco, Inc.|Processing biomass|

---

NZ706072A|2013-03-08|2018-12-21|Xyleco Inc|Equipment protecting enclosures|

---

MX356911B|2012-10-10|2018-06-19|Xyleco Inc|Treating biomass.|

---

KR20150067144A|2012-10-10|2015-06-17|질레코 인코포레이티드|Equipment protecting enclosures|

---

US9119281B2|2012-12-03|2015-08-25|Varian Medical Systems, Inc.|Charged particle accelerator systems including beam dose and energy compensation and methods therefor|

---

SG10201707552VA|2013-05-17|2017-11-29|Xyleco Inc|Processing biomass|

---

EP3119679A4|2014-03-21|2017-10-25|Xyleco, Inc.|Method and structures for processing materials|

---

AU2015292799B2|2014-07-21|2019-06-13|Xyleco, Inc.|Processing biomass|US20130161531A1|2011-12-22|2013-06-27|Danny Lee Haile|Devices and methods for curing nail gels|

---

NZ706072A|2013-03-08|2018-12-21|Xyleco Inc|Equipment protecting enclosures|

---

MX356911B|2012-10-10|2018-06-19|Xyleco Inc|Treating biomass.|

---

US10689196B2|2012-10-10|2020-06-23|Xyleco, Inc.|Processing materials|

---

KR20150067144A|2012-10-10|2015-06-17|질레코 인코포레이티드|Equipment protecting enclosures|

---

US20190232228A1|2013-03-08|2019-08-01|Xyleco, Inc.|Controlling process gases|

---

KR20160002751A|2013-04-26|2016-01-08|질레코 인코포레이티드|Processing biomass to obtain hydroxylcarboxylic acids|

---

AU2014256919B2|2013-04-26|2018-04-19|Xyleco, Inc.|Processing hydroxy-carboxylic acids to polymers|

---

US20160017444A1|2014-02-19|2016-01-21|Xyleco, Inc.|Processing biomass|

---

JP6033162B2|2013-05-13|2016-11-30|日立造船株式会社|Shield and electron beam container sterilization equipment|

---

US20160130525A1|2013-06-10|2016-05-12|Donald L. Fisk|Continuous dry milling method of whole grain component extraction|

---

FR3015311B1|2013-12-24|2016-01-01|Agronomique Inst Nat Rech|PROCESS FOR FRACTIONING OIL MEALS AND APPLICATIONS THEREOF|

---

CN105934397B|2014-01-27|2018-08-31|株式会社普利司通|Sensor and monitoring system|

---

EP3119679A4|2014-03-21|2017-10-25|Xyleco, Inc.|Method and structures for processing materials|

---

JP2015186235A|2014-03-26|2015-10-22|ソニー株式会社|Image sensor and electronic apparatus|

---

JP5682721B1|2014-03-31|2015-03-11|ソニー株式会社|Industrial robot and its mounting unit|

---

US10086516B2|2014-04-02|2018-10-02|President And Fellows Of Harvard College|Color- or grayscale-sensing, magnetic, mobile, marking robot|

---

JP6305280B2|2014-08-28|2018-04-04|株式会社日立ハイテクサイエンス|X-ray fluorescence analyzer and sample display method thereof|

---

FR3027821B1|2014-10-31|2018-11-16|Centralesupelec|PROCESS FOR PURIFYING OSES|

---

FR3037057B1|2015-06-05|2019-06-14|Degremont|METHOD AND DEVICE FOR HYDROTHERMAL CARBONIZATION WITH OPTIMIZED ENERGY EFFICIENCY|

---

TWI531425B|2015-07-08|2016-05-01|chang-qing Lin|Biological sludge for the production of biomass fuels|

---

US9812282B2|2015-11-26|2017-11-07|Mevex Corporation|System and method for irradiating a product|

---

CN105602773B|2016-02-17|2018-08-03|茗燕生物科技有限公司|Laundry sheet intellectualized production system|

---

CN105779070A|2016-05-04|2016-07-20|广州市威士环保科技有限公司|Method for generating energy from leather waste|

---

WO2017207872A1|2016-05-31|2017-12-07|Heidi Piili|Process for splitting cellulosic material and process of producing ethanol from cellulosic material|

---

EP3284351B1|2016-08-20|2019-02-27|Bühler AG|Method of pasteurizing and/or sterilising particulate material|

---

JP6751326B2|2016-09-16|2020-09-02|キオクシア株式会社|Substrate processing apparatus and semiconductor device manufacturing method|

---

US10857513B2|2016-11-08|2020-12-08|Anhui Dingliang Technology Energy Co., Ltd.|Biomass granulator|

---

MA40103B1|2017-03-08|2018-11-30|Mustapha Benmoussa|A process for preparing a coating to improve the efficiency and quality of fertilizers|

---

CN108729276A|2017-04-18|2018-11-02|上海众伟生化有限公司|Flaxen fiber biology soil-coating membrane and preparation method thereof|

---

US10485253B2|2017-08-21|2019-11-26|Mustapha Benmoussa|Method of microalgal biomass processing for high-value chemicals production, the resulting composition of butyrogenic algal slowly fermenting dietary fiber, and a way to improve colon health using a slowly fermenting butyrogenic algal dietary fiber|

---

TWI687249B|2017-08-30|2020-03-11|中國商南京中硼聯康醫療科技有限公司|Neutron Capture Therapy System|

---

EP3476973A1|2017-10-25|2019-05-01|L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude|Process chamber and method for purging the same|

---

CN107640527A|2017-10-26|2018-01-30|安徽锐视光电技术有限公司|A kind of wear-resisting material conveying bucket body that shakes applied to bulky grain ore separator|

---

RU189259U1|2018-08-31|2019-05-17|Николай Владиславович Аржанов|Case of radiation protection of the unit for radiation processing of objects|

---

WO2020046170A1|2018-08-31|2020-03-05|Николай Владиславович АРЖАНОВ|Housing for radiological protection unit for radiological treatment of objects|

---

US11261315B1|2019-01-09|2022-03-01|North Carolina Agricultural And Technical State University|Environmentally friendly asphalt binder additive|

---

WO2020159964A1|2019-01-28|2020-08-06|University Of Florida Research Foundation|Method for fermentation under reduced pressure|

---

CN110208395B|2019-05-16|2021-10-26|湖北祺美中检联检测有限公司|Gas chromatograph with protection architecture|

---

CN110820402B|2019-11-15|2021-07-20|蚌埠市乐力滤清器有限公司|Filter paper made of oilseed residue|

---

WO2021131181A1|2019-12-27|2021-07-01|三菱ケミカル株式会社|Degradation accelerator for biodegradable resin, biodegradable resin composition, biodegradable resin molded product, and method for producing degradation accelerator for biodegradable resin|

---

CN112459510A|2020-11-19|2021-03-09|合肥瑞悦工贸有限公司|Protector is used in concrete feeding|

---

CN113061449B|2021-03-30|2021-10-01|遵义师范学院|Biomass charcoal preparation facilities of hot pepper straw|

法律状态:
2018-03-06| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2018-03-13| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2018-03-20| B06I| Publication of requirement cancelled [chapter 6.9 patent gazette]|Free format text: ANULADA A PUBLICACAO CODIGO 6.6.1 NA RPI NO 2462 DE 13/03/2018 POR TER SIDO INDEVIDA. |

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2020-08-04| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2020-11-24| B11B| Dismissal acc. art. 36, par 1 of ipl - no reply within 90 days to fullfil the necessary requirements|

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2021-10-13| B350| Update of information on the portal [chapter 15.35 patent gazette]|

优先权:

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申请号 | 申请日 | 专利标题

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US201261711807P| true| 2012-10-10|2012-10-10|

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US201261711801P| true| 2012-10-10|2012-10-10|

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US201361774746P| true| 2013-03-08|2013-03-08|

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US201361774735P| true| 2013-03-08|2013-03-08|

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US201361774731P| true| 2013-03-08|2013-03-08|

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US201361774684P| true| 2013-03-08|2013-03-08|

---

US201361774723P| true| 2013-03-08|2013-03-08|

---

US201361774740P| true| 2013-03-08|2013-03-08|

---

US201361774780P| true| 2013-03-08|2013-03-08|

---

US201361774775P| true| 2013-03-08|2013-03-08|

---

US201361774761P| true| 2013-03-08|2013-03-08|

---

US201361774744P| true| 2013-03-08|2013-03-08|

---

US201361774754P| true| 2013-03-08|2013-03-08|

---

US201361774752P| true| 2013-03-08|2013-03-08|

---

US201361774750P| true| 2013-03-08|2013-03-08|

---

US201361774773P| true| 2013-03-08|2013-03-08|

---

US201361793336P| true| 2013-03-15|2013-03-15|

---

PCT/US2013/064317|WO2014059131A1|2012-10-10|2013-10-10|Equipment protecting enclosures|

---